Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/12756
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dc.contributor.authorAltınbaş, Bekir Fırattr
dc.contributor.authorOrak, Cerentr
dc.contributor.authorÖkten, Hatice Esertr
dc.contributor.authorYüksel, Aslıtr
dc.date.accessioned2023-01-17T07:04:51Z-
dc.date.available2023-01-17T07:04:51Z-
dc.date.issued2022-12-
dc.identifier.urihttps://doi.org/10.1021/acsomega.2c06046-
dc.identifier.urihttps://hdl.handle.net/11147/12756-
dc.descriptionThis study was financially supported through the project The Scientific and Technological Research Council of Turkey-TUBITAK (Project No. 119N310).en_US
dc.description.abstractA novel hybrid adsorption-electrodialysis (AdED) system to remove environmentally harmful boron from geothermal brine was designed and effective operating parameters such as pH, voltage, and flow rate were studied. A cellulose-based adsorbent was synthesized from glycidyl methacrylate (GMA) grafted cellulose and modified with a boron selective n-methyl-d-glucamine (NMDG) group and characterized with SEM-EDX, FT-IR, and TGA analyses. Batch adsorption studies revealed that cellulose-based adsorbent showed a remarkable boron removal capacity (19.29 mg/g), a wide stable operating pH range (2-10), and an adsorption process that followed the Freundlich isotherm (R2= 0.95) and pseudo-second-order kinetics (R2= 0.99). In the hybrid AdED system, the optimum operating parameters for boron removal were found to be a pH of 10, a voltage of 10 V, a flow rate of 100 mL/min, and an adsorbent dosage of 4 g/L. The presence of the adsorbent in the hybrid system increased boron removal from real geothermal brine (containing 199 ppm boron) from 7.2% to 73.3%. The results indicate that the designed AdED system performs better than bare electrodialysis for boron removal from ion-rich real geothermal brine while utilizing environmentally friendly cellulose-based adsorbent.en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relationTürkiye’de Gediz Graben’Inde Yüksek Sıcaklıklı Jeotermal Enerji Sistemlerinin Sürdürülebilir Gelişimi Için Jeotermal Akışkanlarda Bor Yönetimitr
dc.relation.ispartofACS Omegaen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBoronen_US
dc.subjectGeothermal brineen_US
dc.subjectAdsorptionen_US
dc.titleNovel hybrid adsorption-electrodialysis (AdED) system for removal of boron from geothermal brineen_US
dc.typeArticleen_US
dc.authorid0000-0001-8864-5943en_US
dc.authorid0000-0001-7511-940Xen_US
dc.authorid0000-0002-9273-2078en_US
dc.institutionauthorAltınbaş, Bekir Fırattr
dc.institutionauthorOrak, Cerentr
dc.institutionauthorÖkten, Hatice Esertr
dc.institutionauthorYüksel, Aslıtr
dc.departmentİzmir Institute of Technology. Environmental Engineeringen_US
dc.departmentİzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.wosWOS:000901666200001-
dc.identifier.scopus2-s2.0-85143593666-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıtr
dc.identifier.doi10.1021/acsomega.2c06046-
dc.identifier.pmid36530257-
dc.relation.issn2470-1343en_US
dc.description.volume7en_US
dc.description.issue49en_US
dc.description.startpage45422en_US
dc.description.endpage45431en_US
dc.relation.grantno119N310en_US
dc.identifier.scopusqualityQ1-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.grantfulltextopen-
item.languageiso639-1en-
crisitem.author.dept01. Izmir Institute of Technology-
crisitem.author.dept03.07. Department of Environmental Engineering-
crisitem.author.dept03.02. Department of Chemical Engineering-
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Environmental Engineering / Çevre Mühendisliği
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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