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dc.contributor.authorKıymaz, D.
dc.contributor.authorYağmurcukardeş, Mehmet
dc.contributor.authorTomak, Aysel
dc.contributor.authorŞahin, Hasan
dc.contributor.authorSenger, Ramazan Tuǧrul
dc.contributor.authorPeeters, François M.
dc.contributor.authorZareie, Hadi M.
dc.contributor.authorZafer, Ceylan
dc.date.accessioned2017-07-24T13:09:50Z
dc.date.available2017-07-24T13:09:50Z
dc.date.issued2016-10-11
dc.identifier.citationKıymaz, D., Yağmurcukardeş, M., Tomak, A., Şahin, H., Senger, R.T., Peeters, F.M., Zareie, H.M., and Zafer, C. (2016). Controlled growth mechanism of poly (3-hexylthiophene) nanowires. Nanotechnology, 27(45). doi:10.1088/0957-4484/27/45/455604en_US
dc.identifier.issn0957-4484
dc.identifier.urihttps://doi.org/10.1088/0957-4484/27/45/455604
dc.identifier.urihttp://hdl.handle.net/11147/6003
dc.description.abstractSynthesis of 1D-polymer nanowires by a self-assembly method using marginal solvents is an attractive technique. While the formation mechanism is poorly understood, this method is essential in order to control the growth of nanowires. Here we visualized the time-dependent assembly of poly (3-hexyl-thiophene-2,5-diyl) (P3HT) nanowires by atomic force microscopy and scanning tunneling microscopy. The assembly of P3HT nanowires was carried out at room temperature by mixing cyclohexanone (CHN), as a poor solvent, with polymer solution in 1,2-dichlorobenzene (DCB). Both π-π stacking and planarization, obtained at the mix volume ratio of P3HT (in DCB):CHN (10:7), were considered during the investigation. We find that the length of nanowires was determined by the ordering of polymers in the polymer repetition direction. Additionally, our density functional theory calculations revealed that the presence of DCB and CHN molecules that stabilize the structural distortions due to tail group of polymers was essential for the core-wire formation.en_US
dc.description.sponsorshipFlemish Science Foundation (FWO-Vl); Methusalem foundation of the Flemish government; Hercules Foundation; FWO Pegasus-Long Marie Curie Fellowship ; TUBITAK (114F397); Scientific Research Project Fund of Ege University (12GEE011)en_US
dc.language.isoengen_US
dc.publisherIOP Publishingen_US
dc.relationinfo:eu-repo/grantAgreement/TUBITAK/MFAG/114F397en_US
dc.relation.isversionof10.1088/0957-4484/27/45/455604en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectNanowiresen_US
dc.subjectSelf assembly methoden_US
dc.subjectPolymer nanowiresen_US
dc.subjectStructural distortionsen_US
dc.subjectPoly(3-hexyl-thiophene)en_US
dc.titleControlled growth mechanism of poly (3-hexylthiophene) nanowiresen_US
dc.typearticleen_US
dc.contributor.authorIDTR130774en_US
dc.contributor.authorIDTR2199en_US
dc.contributor.authorIDTR166094en_US
dc.contributor.iztechauthorYağmurcukardeş, Mehmet
dc.contributor.iztechauthorTomak, Aysel
dc.contributor.iztechauthorSenger, Ramazan Tuǧrul
dc.contributor.iztechauthorZareie, Hadi M.
dc.relation.journalNanotechnologyen_US
dc.contributor.departmentİYTE, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume27en_US
dc.identifier.issue45en_US
dc.identifier.wosWOS:000386132600003
dc.identifier.scopusSCOPUS:2-s2.0-84991607100
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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