Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/5969
Title: Air and seawater pollution and air–sea gas exchange of persistent toxic substances in the Aegean Sea: spatial trends of PAHs, PCBs, OCPs and PBDEs
Authors: Lammel, Gerhard
Audy, Ondrej
Besis, Athanasios
Efstathiou, Christos
Eleftheriadis, Kostas
Kohoutek, Jiri
Kukucka, Petr
Mulder, Marie D.
Pribylova, Petra
Prokes, Roman
Rusina, Tatsiana P.
Samara, Constantini
Sofuoğlu, Aysun
Sofuoğlu, Sait Cemil
Taşdemir, Yücel
Vassilatou, Vassiliki
Voutsa, Dimitra
Vrana, Branislav
Sofuoğlu, Aysun
Sofuoğlu, Sait Cemil
Izmir Institute of Technology. Chemical Engineering
Keywords: Aegean Sea
Air–sea gas exchange
Deposition
Fugacity ratios
Passive sampling
Issue Date: Aug-2015
Publisher: Springer Verlag
Source: Lammel, G., Audy, O., Besis, A., Efstathiou, C., Eleftheriadis, K., Kohoutek, J., Kukucka, P.,...Vrana, B. (2015). Air and seawater pollution and air–sea gas exchange of persistent toxic substances in the Aegean Sea: spatial trends of PAHs, PCBs, OCPs and PBDEs. Environmental Science and Pollution Research, 22(15), 11301-11313. doi:10.1007/s11356-015-4363-4
Abstract: Near-ground air (26 substances) and surface seawater (55 substances) concentrations of persistent toxic substances (PTS) were determined in July 2012 in a coordinated and coherent way around the Aegean Sea based on passive air (10 sites in 5 areas) and water (4 sites in 2 areas) sampling. The direction of air–sea exchange was determined for 18 PTS. Identical samplers were deployed at all sites and were analysed at one laboratory. hexachlorobenzene (HCB), hexachlorocyclohexanes (HCHs) as well as dichlorodiphenyltrichloroethane (DDT) and its degradation products are evenly distributed in the air of the whole region. Air concentrations of p,p′-dichlorodiphenyldichloroethylene (p,p′-DDE) and o,p′-DDT and seawater concentrations of p,p′-DDE and p,p′-DDD were elevated in Thermaikos Gulf, northwestern Aegean Sea. The polychlorinated biphenyl (PCB) congener pattern in air is identical throughout the region, while polybrominated diphenylether (PBDE)patterns are obviously dissimilar between Greece and Turkey. Various pollutants, polycyclic aromatic hydrocarbons (PAHs), PCBs, DDE, and penta- and hexachlorobenzene are found close to phase equilibrium or net-volatilisational (upward flux), similarly at a remote site (on Crete) and in the more polluted Thermaikos Gulf. The results suggest that effective passive air sampling volumes may not be representative across sites when PAHs significantly partitioning to the particulate phase are included.
URI: http://doi.org/10.1007/s11356-015-4363-4
http://hdl.handle.net/11147/5969
ISSN: 0944-1344
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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