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https://hdl.handle.net/11147/5889| Title: | Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy | Authors: | Kuş, Melih Artok, Levent Aygün, Muhittin |
Keywords: | Catalysis Palladium compounds Stereoselectivity Alkoxycarbonylation Diastereoselective |
Publisher: | American Chemical Society | Source: | Kuş, M., Artok, L., and Aygün, M. (2015). Palladium-catalyzed alkoxycarbonylation of conjugated enyne oxiranes: A diastereoselective method for the synthesis of 7-hydroxy-2,3,5-trienoates. Journal of Organic Chemistry, 80(11), 5494-5506. doi:10.1021/acs.joc.5b00382 | Abstract: | Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured 7-hydroxy-2,3,5-trienoates. The reactions proceeded in a highly stereoselective manner, possibly through sequential formation of π-allylpalladium and σ-vinylallenyl palladium complexes. The major diastereomeric form of the product is determined by the configuration of the alkenyl moiety of the substrate. | URI: | https://doi.org/10.1021/acs.joc.5b00382 http://hdl.handle.net/11147/5889 |
ISSN: | 0022-3263 |
| Appears in Collections: | Chemistry / Kimya PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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