Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/5889
Title: Palladium-catalyzed alkoxycarbonylation of conjugated enyne oxiranes: A diastereoselective method for the synthesis of 7-hydroxy-2,3,5-trienoates
Authors: Kuş, Melih
Artok, Levent
Aygün, Muhittin
Keywords: Catalysis
Palladium compounds
Stereoselectivity
Alkoxycarbonylation
Diastereoselective
Issue Date: 5-Jun-2015
Publisher: American Chemical Society
Source: Kuş, M., Artok, L., and Aygün, M. (2015). Palladium-catalyzed alkoxycarbonylation of conjugated enyne oxiranes: A diastereoselective method for the synthesis of 7-hydroxy-2,3,5-trienoates. Journal of Organic Chemistry, 80(11), 5494-5506. doi:10.1021/acs.joc.5b00382
Abstract: Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured 7-hydroxy-2,3,5-trienoates. The reactions proceeded in a highly stereoselective manner, possibly through sequential formation of π-allylpalladium and σ-vinylallenyl palladium complexes. The major diastereomeric form of the product is determined by the configuration of the alkenyl moiety of the substrate.
URI: https://doi.org/10.1021/acs.joc.5b00382
http://hdl.handle.net/11147/5889
ISSN: 0022-3263
Appears in Collections:Chemistry / Kimya
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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