Palladium-Catalyzed Alkoxycarbonylation of (z)-2 Carbonates Leading To 2,3,5-Trienoates

Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2829

Title:	Palladium-Catalyzed Alkoxycarbonylation of (z)-2 Carbonates Leading To 2,3,5-Trienoates
Authors:	Akpınar, G. Eray Kuş, Melih Üçüncü, Muhammed Karakuş, Erman Artok, Levent
Keywords:	Alkoxycarbonylation Carbonates
Publisher:	American Chemical Society
Source:	Akpınar, G. E., Kuş, M., Üçüncü, M., Karakuş, E., and Artok, L. (2011). Palladium-catalyzed alkoxycarbonylation of (Z)-2-En-4-yn carbonates leading to 2,3,5-trienoates. Organic Letters, 13 (4), 748-751. doi:10.1021/ol102989q
Abstract:	Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with E-configured enyne carbonates may indicate that the reaction is promoted via the cooperative coordination of palladium with both alkynyl and carbonate moieties.
URI:	http://doi.org/10.1021/ol102989q http://hdl.handle.net/11147/2829
ISSN:	1523-7060 1523-7052 1523-7060
Appears in Collections:	Chemistry / Kimya PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection