Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2829
Title: Palladium-catalyzed alkoxycarbonylation of (Z)-2-En-4-yn carbonates leading to 2,3,5-trienoates
Authors: Akpınar, G. Eray
Kuş, Melih
Üçüncü, Muhammed
Karakuş, Erman
Artok, Levent
Keywords: Alkoxycarbonylation
Carbonates
Issue Date: 18-Feb-2011
Publisher: American Chemical Society
Source: Akpınar, G. E., Kuş, M., Üçüncü, M., Karakuş, E., and Artok, L. (2011). Palladium-catalyzed alkoxycarbonylation of (Z)-2-En-4-yn carbonates leading to 2,3,5-trienoates. Organic Letters, 13 (4), 748-751. doi:10.1021/ol102989q
Abstract: Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with E-configured enyne carbonates may indicate that the reaction is promoted via the cooperative coordination of palladium with both alkynyl and carbonate moieties.
URI: http://doi.org/10.1021/ol102989q
http://hdl.handle.net/11147/2829
ISSN: 1523-7060
1523-7052
1523-7060
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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