Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/10444
Title: Palladium-catalysed regio- and stereoselective arylative substitution of gamma,delta-epoxy-alpha,beta-unsaturated esters and amides by sodium tetraaryl borates
Authors: Bilgi, Yasemin
Kuş, Melih
Artok, Levent
Issue Date: 2020
Publisher: Royal Society of Chemistry
Abstract: Palladium-catalysed reactions of gamma,delta-epoxy-alpha,beta-unsaturated esters and amides with NaBAr(4)reagents proceeded regio- and stereoselectively, producing allylic homoallyl alcohols with aryl-substituents in the allylic position for a wide range of substrates. AsPh(3)was found to be a competent ligand for the arylation reaction, whereas phosphine ligand/Lewis acidic organoboron combinations favoured the substitution reaction by oxygen nucleophiles (e.g.H2O, ROH).
URI: https://doi.org/10.1039/d0ob01226b
https://hdl.handle.net/10444
ISSN: 1477-0520
1477-0539
Appears in Collections:Chemistry / Kimya
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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