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https://hdl.handle.net/11147/9530
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DC Field | Value | Language |
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dc.contributor.author | Fırıncı, Erkan | - |
dc.contributor.author | Sevinçek, Resul | - |
dc.contributor.author | Bursalı, Banu | - |
dc.contributor.author | Özgener, Hüseyin | - |
dc.contributor.author | Burgaz, Osman | - |
dc.contributor.author | Şen, Ceren | - |
dc.contributor.author | Şahin, Yüksel | - |
dc.date.accessioned | 2020-07-25T22:16:53Z | - |
dc.date.available | 2020-07-25T22:16:53Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.issn | 1873-3255 | - |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2019.119038 | - |
dc.identifier.uri | https://hdl.handle.net/11147/9530 | - |
dc.description.abstract | The derivatives of diazatriborolidine are a class of 5-membered heterocyclic compounds containing a ring with two nitrogen atoms and three boron atoms. The 1,3,2,4,5-diazatriborolidine derivatives were synthesized from 1,2-bis(N-lithium-arylamino) diborane(4) and dichloro-dimethylaminoborane with high yield. The structures of these new derivatives were determined using nuclear magnetic resonance (NMR) spectroscopy. The molecular structures of 3a, 3b, 3d, 4b and 4c were determined using single-crystal X-ray diffraction. Their structural features were discussed and compared with similar diazatriborolidines. In addition, the enthalpy of formation of B and N atoms containing five membered heterocycles were calculated theoretically for the first time. Also, an easy and efficient synthesis route has been reported for preparation of 1,3,2,4,5-diazatriborolidine derivatives. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Azaborolidine | en_US |
dc.subject | Diazatriborole | en_US |
dc.subject | Enthalpy of formation | en_US |
dc.subject | Heterocyclic | en_US |
dc.title | Synthesis and structures of 1,3,2,4,5-diazatriborolidines | en_US |
dc.type | Article | en_US |
dc.institutionauthor | Özgener, Hüseyin | - |
dc.department | İzmir Institute of Technology. Chemistry | en_US |
dc.identifier.volume | 496 | en_US |
dc.identifier.wos | WOS:000487818900019 | en_US |
dc.identifier.scopus | 2-s2.0-85069960430 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1016/j.ica.2019.119038 | - |
dc.relation.doi | 10.1016/j.ica.2019.119038 | en_US |
dc.coverage.doi | 10.1016/j.ica.2019.119038 | en_US |
dc.identifier.wosquality | Q2 | - |
dc.identifier.scopusquality | Q2 | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | Article | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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1-s2.0-S0020169319308370-main.pdf | 678.77 kB | Adobe PDF | View/Open |
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