Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9530
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dc.contributor.authorFırıncı, Erkan-
dc.contributor.authorSevinçek, Resul-
dc.contributor.authorBursalı, Banu-
dc.contributor.authorÖzgener, Hüseyin-
dc.contributor.authorBurgaz, Osman-
dc.contributor.authorŞen, Ceren-
dc.contributor.authorŞahin, Yüksel-
dc.date.accessioned2020-07-25T22:16:53Z-
dc.date.available2020-07-25T22:16:53Z-
dc.date.issued2019-
dc.identifier.issn0020-1693-
dc.identifier.issn1873-3255-
dc.identifier.urihttps://doi.org/10.1016/j.ica.2019.119038-
dc.identifier.urihttps://hdl.handle.net/11147/9530-
dc.description.abstractThe derivatives of diazatriborolidine are a class of 5-membered heterocyclic compounds containing a ring with two nitrogen atoms and three boron atoms. The 1,3,2,4,5-diazatriborolidine derivatives were synthesized from 1,2-bis(N-lithium-arylamino) diborane(4) and dichloro-dimethylaminoborane with high yield. The structures of these new derivatives were determined using nuclear magnetic resonance (NMR) spectroscopy. The molecular structures of 3a, 3b, 3d, 4b and 4c were determined using single-crystal X-ray diffraction. Their structural features were discussed and compared with similar diazatriborolidines. In addition, the enthalpy of formation of B and N atoms containing five membered heterocycles were calculated theoretically for the first time. Also, an easy and efficient synthesis route has been reported for preparation of 1,3,2,4,5-diazatriborolidine derivatives.en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAzaborolidineen_US
dc.subjectDiazatriboroleen_US
dc.subjectEnthalpy of formationen_US
dc.subjectHeterocyclicen_US
dc.titleSynthesis and structures of 1,3,2,4,5-diazatriborolidinesen_US
dc.typeArticleen_US
dc.institutionauthorÖzgener, Hüseyin-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume496en_US
dc.identifier.wosWOS:000487818900019en_US
dc.identifier.scopus2-s2.0-85069960430en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.ica.2019.119038-
dc.relation.doi10.1016/j.ica.2019.119038en_US
dc.coverage.doi10.1016/j.ica.2019.119038en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ2-
item.fulltextWith Fulltext-
item.grantfulltextopen-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeArticle-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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