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Title: | Cleavage of ring A and formation of an unusual nor-triterpene skeleton via the Baeyer-Villiger reaction | Authors: | Tağ, Özgür Çağır, Ali Khan, Ikhlas A. Bedir, Erdal |
Keywords: | 3,5-Seco-4-nor-triterpenes Baeyer-Villiger Cycloastragenol Semi-synthesis Ring opening |
Publisher: | Elsevier Ltd. | Source: | Tağ, Ö., Çağır, A., Khan, I. A. and Bedir, E. (2012). Cleavage of ring A and formation of an unusual nor-triterpene skeleton via the Baeyer-Villiger reaction. Tetrahedron Letters, 53(44), 5864-5867. doi:10.1016/j.tetlet.2012.08.068 | Abstract: | With the aim to generate a compound library for our biological screening studies, cycloastragenol was subjected to chemical transformation studies. The Baeyer-Villiger oxidation experiments provided an interesting 3,5-seco-4-nor-triterpene skeleton via ring opening followed by an unusual rearrangement. A new methodology is described for transforming triterpenoids into 3,5-seco-4-nor derivatives. | URI: | http://dx.doi.org/10.1016/j.tetlet.2012.08.068 http://hdl.handle.net/11147/5228 |
ISSN: | 0040-4039 1873-3581 |
Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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