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https://hdl.handle.net/11147/4754| Title: | Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5 | Authors: | Eanes, Mehtap Kolis, Joseph W. |
Keywords: | Antiferromagnetic coupling Crystal structure Hydrothermal method Lithium compounds Electronic configuration |
Publisher: | Elsevier Ltd. | Source: | Emirdag-Eanes, M., and Kolis, J. W. (2004). Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5. Journal of Alloys and Compounds, 370(1-2), 90-93. doi:10.1016/j.jallcom.2003.09.027 | Abstract: | The new compound Li2VGeO5 with a layered structure has been synthesized at 580°C via the hydrothermal method. The compound crystallizes in the space group P4/n of the tetragonal system with two formula units in a cell of dimensions a=6.5187(9)Å, c=4.5092(9)Å (T=298K), V=191.61(5)Å3. The structure is composed of layers made of repeating [(VO5)(GeO4)]1- units. Li+ ions reside between the layers. The magnetic susceptibility data show an antiferromagnetic coupling below 5K with C=0.47emuKmol-1, and θ=-13K with μeff=1.89μB for each Li 2VGeO5 unit. | URI: | http://doi.org/10.1016/j.jallcom.2003.09.027 http://hdl.handle.net/11147/4754 |
ISSN: | 0925-8388 0925-8388 |
| Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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