Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4731
Title: Synthesis and characterization of two oxo-bridged oxo(arylimido) [tris(3,5-dimethylpyrazolyI)borato]molybdenum(V) complexes and crystal structure of [MoTp*(O)CI](µ-O)[MoTp*(CI)(?NC6H 4OMe)]
Authors: Topaloğlu, Işıl
Günyar, Alev
Jeffery, John C.
Hamidov, Hayrullah
Topaloğlu, Işıl
Günyar, Alev
Keywords: Organometallics
Biochemical catalysis
Ligands
Organometallic chemistry
Polynuclear complexes
Issue Date: Oct-2004
Publisher: Springer Verlag
Source: Topaloğlu, I., Günyar, A., Jeffery, J. C., and Hamidov, H. (2004). Synthesis and characterization of two oxo-bridged oxo(arylimido) [tris(3,5-dimethylpyrazolyI)borato]molybdenum(V) complexes and crystal structure of [MoTp*(O)CI](μ-O)[MoTp*(CI)(≡NC6H 4OMe)]. Transition Metal Chemistry, 29(7), 780-785. doi:10.1007/s11243-004-9171-5
Abstract: Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate] with p-methoxy and p-nitroaniline in the presence of Et3N under N2, afforded the oxo-bridged oxo(arylimido) molybdenum(V) complexes, [MoTp*(O)Cl](μ- O)[MoTp*(Cl)(≡NC6H4R)] (1, R = OMe; 2, R = NO2). The new compounds were characterized by elemental analysis, i.r., mass, and 1H-n.m.r. spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](μ-O)[MoTp*(Cl) (≡NC6H4OMe)] was carried out to confirm that there is a Mo - O - Mo bridge and a near linear arylimido group in the structure.
URI: http://doi.org/10.1007/s11243-004-9171-5
http://hdl.handle.net/11147/4731
ISSN: 0340-4285
1572-901X
0340-4285
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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