Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4651
Title: Tin soaps in emulsion PVC heat stabilization
Authors: Arkış, Esen
Balköse, Devrim
Balköse, Devrim
Keywords: Poly(vinylchloride)
Stabilization
PVC
Issue Date: Mar-2002
Publisher: John Wiley and Sons Inc.
Source: Arkış, E., and Balköse, D. (2002). Tin soaps in emulsion PVC heat stabilization. Advances in Polymer Technology, 21(1), 65-73. doi:10.1002/adv.10008
Abstract: In this study, the effect of a liquid stabilizer based on organotins on PVC heat stability is investigated. Control and films with tin soap heat stabilizer Sn500K were prepared by solvent casting and they were heated at 160 and 180°C for different time periods. X-ray fluorescence spectroscopy analysis showed that tin was present in Sn500K and it was lead-free. DSC analysis showed that glass-transition temperature of films with Sn500K increased from 67 to 75-85°C by heating for 15 min at 180°C. IR spectroscopy indicated that concentration of carboxylate groups of Sn500K decreased with heating. Films with Sn500K did not degrade for short heating periods; however, degradation occurred in long heating times. Low concentration of Sn500K was recommended, since at high levels incompatibility with PVC and acceleration of degradation was observed. In the high temperature range, control and stabilized samples degraded in the same manner in two steps
URI: http://doi.org/10.1002/adv.10008
http://hdl.handle.net/11147/4651
ISSN: 0730-6679
0730-6679
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Files in This Item:
File Description SizeFormat 
4651.pdfMakale176.08 kBAdobe PDFThumbnail
View/Open
Show full item record

CORE Recommender

SCOPUSTM   
Citations

5
checked on Oct 16, 2021

WEB OF SCIENCETM
Citations

8
checked on Oct 16, 2021

Page view(s)

28
checked on Oct 20, 2021

Download(s)

34
checked on Oct 20, 2021

Google ScholarTM

Check

Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.