Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4531
Title: Solvent diffusion in amorphous polymers: Polyvinyl acetate-toluene system
Authors: Tıhmınlıoğlu, Funda
Danner, Ronald P.
Lützow, Norbert
Duda, John Larry
Keywords: Polyvinyl acetates
Amorphous materials
Correlation methods
Diffusion
Gas chromatography
Publisher: John Wiley and Sons Inc.
Source: Tıhmınlıoğlu, F., Danner, R. P., Lützow, N., and Duda, J. L. (2000). Solvent diffusion in amorphous polymers: Polyvinyl acetate-toluene system. Journal of Polymer Science, Part B: Polymer Physics, 38(18), 2429-2435. doi:10.1002/1099-0488(20000915)38:18<2429
Abstract: In a previous publication (Tihminlioglu et al., J Polym Sci Part B: Polym Phys 1997, 35, 1279), we presented an extensive analysis of the polyvinyl acetate-toluene system. The inverse gas chromatography (IGC) technique was used to measure phase equilibria and diffusion coefficients above and near the glass-transition temperature of a polymer. At temperatures above the glass transition, the capillary column model developed by Pawlisch et al. (Macromolecules 1987, 20, 1564) was used. For the finite concentration region, the modified model of Tihminlioglu and Danner (J Chromatogr A 1999, 845, 93) was applied. Data obtained with the IGC method were in agreement with data measured with the gravimetric and piezoelectric sorption techniques. In this work, we revisit the partition coefficient issue and provide some new data at lower temperatures. At temperatures near the glass-transition temperature, the modification of the capillary column model proposed by Vrentas et al. (Macromolecules 1993, 26, 6670) was used for the infinite dilution region. The diffusion data correlated well with the Vrentas-Duda free-volume model.
URI: http://doi.org/10.1002/1099-0488(20000915)38:18<2429
http://hdl.handle.net/11147/4531
ISSN: 0887-6266
1099-0488
0887-6266
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Files in This Item:
File Description SizeFormat 
4531.pdfMakale156.27 kBAdobe PDFThumbnail
View/Open
Show full item record



CORE Recommender

SCOPUSTM   
Citations

19
checked on Apr 14, 2023

WEB OF SCIENCETM
Citations

19
checked on Oct 26, 2024

Page view(s)

310
checked on Oct 28, 2024

Download(s)

252
checked on Oct 28, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.