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https://hdl.handle.net/11147/4504| Title: | Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(?5-C2B 9H10Me2)] | Authors: | Topaloğlu, Işıl | Keywords: | Synthesis(Chemistry) | Publisher: | Marcel Dekker Inc. | Source: | Topaloğlu, I. (1996). Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(η5-C2B 9H10Me2)]. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26(8), 1295-1305. doi:10.1080/00945719608005125 | Abstract: | In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands. | URI: | http://doi.org/10.1080/00945719608005125 http://hdl.handle.net/11147/4504 |
ISSN: | 0094-5714 |
| Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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