Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4504
Title: Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(?5-C2B 9H10Me2)]
Authors: Topaloğlu, Işıl
Topaloğlu, Işıl
Izmir Institute of Technology. Chemistry
Keywords: Synthesis(Chemistry)
Issue Date: 1996
Publisher: Marcel Dekker Inc.
Source: Topaloğlu, I. (1996). Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(η5-C2B 9H10Me2)]. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26(8), 1295-1305. doi:10.1080/00945719608005125
Abstract: In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.
URI: http://doi.org/10.1080/00945719608005125
http://hdl.handle.net/11147/4504
ISSN: 0094-5714
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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