Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2460
Title: Reactions of the solvent-stabilized compound [MoOCl2(THF)2] with aromatic nitrogen donor ligands: Spectroscopic characterization and semiempirical AM1* calculations
Authors: Kılıçkaya, Gülşah
Doğan, Başak
Acar, Nursel
Sözüer, Hikmet Işıl
Kılıçkaya, Gülşah
Doğan, Başak
Sözüer, Hikmet Işıl
Izmir Institute of Technology. Chemistry
Keywords: Mo(VI) complexes
Oxo-imido complexes
Oxomolybdenum complexes
Oxygen atom
Issue Date: Oct-2009
Publisher: TUBITAK
Source: Kılıçkaya, G., Doğan, B., Acar, N., and Sözüer, H. I. (2009). Reactions of the solvent-stabilized compound [MoOCl2(THF)2] with aromatic nitrogen donor ligands: Spectroscopic characterization and semiempirical AM1* calculations. Turkish Journal of Chemistry, 33(5), 693-708. doi:10.3906/kim-0812-73
Abstract: Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2]withP Ph3 yielded the oxomolybdenum(IV) species [MoOCl2 (THF)2](1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl2 (=NC6 H4 CN)] 2,[MoOCl2 (CNC6 H4 OH)] 3,[MoOCl2 (=NC6 H4 NH2)] 4,and [MoOCl2 (=NC6 H4 OCH3)] 5, were synthesized by the reactions of [MoOCl2 (THF)2]with XC6 H4 Y(X =NH2, Y = CN; X= CN, Y = OH; X = Y = NH2;X=NH2,Y=OCH3). All the new compounds were characterized by elemental analyses, and FTIR, UV-Vis, and 1 H and 13 C-NMR spectra. Geometrical parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer between the Mo center and the phenyl ring.
URI: http://doi.org/10.3906/kim-0812-73
http://hdl.handle.net/11147/2460
ISSN: 1300-0527
1300-0527
1303-6130
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
TR Dizin İndeksli Yayınlar / TR Dizin Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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