Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2119
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dc.contributor.authorAksın, Özge-
dc.contributor.authorTürkmen, Hayati-
dc.contributor.authorArtok, Levent-
dc.contributor.authorÇetinkaya, Bekir-
dc.contributor.authorNi, Chaoying-
dc.contributor.authorBüyükgüngör, Orhan-
dc.contributor.authorÖzkal, Erhan-
dc.date.accessioned2016-08-16T10:46:57Z
dc.date.available2016-08-16T10:46:57Z
dc.date.issued2006-06-
dc.identifier.citationAksın, O., Türkmen, H., Artok, L., Çetinkaya, B., Ni, C., Büyükgüngör, O., and Özkal, E. (2006). Effect of immobilization on catalytic characteristics of saturated Pd-N-heterocyclic carbenes in Mizoroki-Heck reactions. Journal of Organometallic Chemistry, 691(13), 3027-3036. doi:10.1016/j.jorganchem.2006.03.012en_US
dc.identifier.issn0022-328X-
dc.identifier.issn0022-328X-
dc.identifier.uri10.1016/j.jorganchem.2006.03.012-
dc.identifier.urihttp://hdl.handle.net/11147/2119-
dc.description.abstractA saturated Pd-N-heterocyclic complex was immobilized on an amorphous silica. The complex itself is of very high thermal stability. However, TEM observations, hot filtration, reusability, and poisoning tests all revealed that the complex acted only as a precatalyst to highly active Pd species in Mizoroki-Heck reactions when immobilized. The complex appears more stable when used under homogeneous reaction conditions. The immobilized complex afforded high turnover numbers, 104-105. The higher turnover frequencies were realized at the lower Pd concentrations, which is a characteristic property of ligand-free Pd catalyzed reactions.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TBAG-2311-103T051), IZTECH (2002-IYTE-36 and 2005-IYTE-18) and Ege University (03/BIL/015)en_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectC-C couplingen_US
dc.subjectHeterocyclic carbeneen_US
dc.subjectHeterogeneous catalysten_US
dc.subjectImmobilized palladiumen_US
dc.subjectMizoroki-Heck reactionen_US
dc.subjectPalladium leachingen_US
dc.subjectOrganometallicsen_US
dc.titleEffect of Immobilization on Catalytic Characteristics of Saturated Pd-N Carbenes in Mizoroki-Heck Reactionsen_US
dc.typeArticleen_US
dc.authoridTR1860-
dc.institutionauthorAksın, Özge-
dc.institutionauthorArtok, Levent-
dc.institutionauthorÖzkal, Erhan-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume691en_US
dc.identifier.issue13en_US
dc.identifier.startpage3027en_US
dc.identifier.endpage3036en_US
dc.identifier.wosWOS:000238309200019-
dc.identifier.scopus2-s2.0-33747421306-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.jorganchem.2006.03.012-
dc.relation.doi10.1016/j.jorganchem.2006.03.012en_US
dc.coverage.doi10.1016/j.jorganchem.2006.03.012-
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ3-
dc.identifier.wosqualityttpTop10%en_US
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.openairetypeArticle-
item.grantfulltextopen-
item.fulltextWith Fulltext-
item.cerifentitytypePublications-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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