Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/1968
Title: Thermal stabilisation of poly(vinyl chloride) by organotin compounds
Authors: Arkış, Esen
Balköse, Devrim
Arkış, Esen
Balköse, Devrim
Keywords: Chemical bonds
Dehydrochlorination
Dioctyl phthalate
Organotin
PVC heat stabilizer
Issue Date: Apr-2005
Publisher: Elsevier Ltd.
Source: Arkış, E., and Balköse, D. (2005). Thermal stabilisation of poly(vinyl chloride) by organotin compounds. Polymer Degradation and Stability, 88(1), 46-51. doi:10.1016/j.polymdegradstab.2004.02.021
Abstract: The effect of LSN 117 (dioctyl tin bis isooctyl thioglycollate, an organotin compound) on the heat stability of plasticised PVC was investigated in this study. The organotin stabiliser had carbonyl and carboxylate groups and PVC contained traces of Fe, Zn, Ca, Cu and Sn. The heat stability of the films were tested at 140 °C and 160 °C or 180 °C by heating in an air circulation oven up to 2 h and by measuring HCl evolved using a Metrohm 763 PVC thermomat and by thermogravimetric analysis. The onset of HCl evolution was at 14.3 and 2.5 h at 140 °C and 160 °C, respectively, for PVC film without LSN117. On the other hand, the film with LSN117 did not evolve HCl in 30.3 h at 140 °C. HCl started to evolve from the films with LSN 117 in 14.3 h at 160 °C. The TGA curve also indicated PVC film with LSN 117 degraded at higher temperatures than control films. LSN 117 was found to be a good heat stabiliser for plasticised PVC and it did not have any detrimental effect on mechanical properties.
URI: https://doi.org/10.1016/j.polymdegradstab.2004.02.021
http://hdl.handle.net/11147/1968
ISSN: 0141-3910
0141-3910
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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