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https://hdl.handle.net/11147/14129
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Durgut, Enes | - |
dc.contributor.author | Zhou, Muchu | - |
dc.contributor.author | Dikici, Betuel Aldemir | - |
dc.contributor.author | Foudazi, Reza | - |
dc.contributor.author | Claeyssens, Frederik | - |
dc.date.accessioned | 2024-01-06T07:21:27Z | - |
dc.date.available | 2024-01-06T07:21:27Z | - |
dc.date.issued | 2024 | - |
dc.identifier.issn | 0927-7757 | - |
dc.identifier.issn | 1873-4359 | - |
dc.identifier.uri | https://doi.org/10.1016/j.colsurfa.2023.132629 | - |
dc.description | Foudazi, Reza/0000-0001-6711-3390; Durgut, Enes/0000-0002-2224-7325; Claeyssens, Frederik/0000-0002-1030-939X; Aldemir Dikici, Betul/0000-0002-5516-469X | en_US |
dc.description.abstract | This study investigates the use of submicron polymeric particles with varying crosslinking densities as the sole stabilizer for producing Polymerized High Internal Phase Emulsions (PolyHIPE). We establish a direct correlation between the crosslinking density and the hydrophilicity of the polymer particles. The hydrophilicity of these particles significantly influences the morphology and rheology of HIPEs. These differences manifest as various morphological variations in the resulting PolyHIPE templates. It was discovered that by increasing the crosslinker weight percentage in the particles from 0 % to 100 %, PolyHIPEs with semi-open, open, and closed porous structures can be obtained. Furthermore, non-crosslinked particles were observed to dissolve in the continuous phase, acting as macromolecular surfactants that generate small pores akin to surfactant-stabilized structures in PolyHIPE. These findings offer fresh insights into the relationship between particle localization at the interface, HIPE rheology, and the formation of pore throats in Pickering PolyHIPEs, leading to the creation of either closed or open porous networks. Additionally, interfacial rheological results demonstrate that particles synthesized with varying monomer-to-crosslinker ratios exhibit different interfacial elasticities, which are linked to PolyHIPE morphology. | en_US |
dc.description.sponsorship | Republic of Turkey-The Ministry of National Education; Engineering and Physical Sciences Research Council [SRF\R1\221053]; Medical Research Council [MR/L012669/1]; Royal Society; [EP/I007695/1] | en_US |
dc.description.sponsorship | The authors gratefully acknowledge the Republic of Turkey-The Ministry of National Education for funding Enes Durgut. They also acknowledge the Engineering and Physical Sciences Research Council (Grant No. EP/I007695/1) and the Medical Research Council (Grant No. MR/L012669/1) for funding the equipment used in this study. Frederik Claeyssens also thanks the Royal Society for funding of a Royal Society Leverhulme Trust Senior Research Fellowship 2022 (SRF\R1\221053) . We also acknowledge Dr. Christopher Holland for conducting bulk rheological measurements. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Pickering Emulsions | en_US |
dc.subject | Rheology | en_US |
dc.subject | Arrested Coalescence | en_US |
dc.subject | Particles | en_US |
dc.subject | Hipe | en_US |
dc.subject | Polyhipe | en_US |
dc.title | Modifying Pickering Polymerized High Internal Phase Emulsion Morphology by Adjusting Particle Hydrophilicity | en_US |
dc.type | Article | en_US |
dc.authorid | 0000-0002-5516-469X | - |
dc.authorid | Foudazi, Reza/0000-0001-6711-3390 | - |
dc.authorid | Claeyssens, Frederik/0000-0002-1030-939X | - |
dc.authorid | Aldemir Dikici, Betul/0000-0002-5516-469X | - |
dc.authorid | Durgut, Enes/0000-0002-2224-7325 | - |
dc.institutionauthor | Aldemir Dikici, Betül | - |
dc.department | İzmir Institute of Technology | en_US |
dc.identifier.volume | 680 | en_US |
dc.identifier.wos | WOS:001106277900001 | - |
dc.identifier.scopus | 2-s2.0-85175560000 | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1016/j.colsurfa.2023.132629 | - |
dc.authorwosid | Dikici, Betül/AAY-9253-2020 | - |
dc.authorwosid | Foudazi, Reza/KHD-9949-2024 | - |
dc.authorwosid | Durgut, Enes/KIA-3031-2024 | - |
dc.authorwosid | Claeyssens, Frederik/E-4781-2011 | - |
dc.identifier.wosquality | Q2 | - |
dc.identifier.scopusquality | Q2 | - |
dc.description.woscitationindex | Science Citation Index Expanded | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
Appears in Collections: | Bioengineering / Biyomühendislik Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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1-s2.0-S0927775723017132-main.pdf | 6.81 MB | Adobe PDF | View/Open |
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