Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/12140
Title: A cyclopalladated BODIPY construct as a fluorescent probe for carbon monoxide
Authors: Çevik Eren, Merve
Eren, Ahmet
Dartar, Suay
Tütüncü, Büşra Buse
Emrullahoğlu, Mustafa
Izmir Institute of Technology
Izmir Institute of Technology
Izmir Institute of Technology
Izmir Institute of Technology
Izmir Institute of Technology
Keywords: BODIPY
Carbon monoxide
Chemosensors
Issue Date: May-2022
Publisher: Wiley
Abstract: By introducing a palladium ion into the backbone of BODIPY, we devised a cyclopalladated BODIPY construct that was almost non-emissive in the absence of any analyte but became highly fluorescent upon interacting with carbon monoxide (CO) in solution and in living cells. A process of ortho-carbonylation and depalladation mediated by the specific binding of CO to palladium, promoted the release of the heavy atom from the fluorophore and consequently generated a fluorescence signal with an exceptionally high (60-fold) enhancement ratio.
URI: https://doi.org/10.1002/ejic.202200093
https://hdl.handle.net/11147/12140
Appears in Collections:Chemistry / Kimya
Photonics / Fotonik
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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