Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/11816
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dc.contributor.authorMorimoto, Tsumoru-
dc.contributor.authorWang, Chuang-
dc.contributor.authorTanimoto, Hiroki-
dc.contributor.authorArtok, Levent-
dc.contributor.authorKakiuchi, Kiyomi-
dc.date.accessioned2021-12-02T18:16:15Z-
dc.date.available2021-12-02T18:16:15Z-
dc.date.issued2021-
dc.identifier.issn0039-7881-
dc.identifier.issn1437-210X-
dc.identifier.urihttps://doi.org/10.1055/a-1468-8377-
dc.identifier.urihttps://hdl.handle.net/11147/11816-
dc.description.abstractThe rhodium(I)-catalyzed reaction of alkynes with aryl-boronic acids in the presence of formaldehyde results in a CO-gas-free arylative dual-carbonylation to produce gamma-butenolide derivatives. The simultaneous loading of phosphine-ligated and phosphine-free rhodium(I) complexes is required for efficient catalysis. The former complex catalyzes the abstraction of a carbonyl moiety from formaldehyde through the activation of its formyl C-H bond (decarbonylation) and the latter catalyzes the subsequent dual-incorporation of the resulting carbonyl unit (carbonylation). The use of larger amounts of the phosphine-ligated rhodium(I) complex generates more carbonyl units, leading to the formation gamma-butenolides via the dual-incorporation of the carbonyl unit.en_US
dc.language.isoenen_US
dc.publisherGeorg Thieme Verlagen_US
dc.relation.ispartofSynthesisen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectC-H activationen_US
dc.subjectDecarbonylationen_US
dc.subjectRhodiumen_US
dc.subjectFormaldehydeen_US
dc.subjectGamma-butenolidesen_US
dc.subjectAlkynesen_US
dc.subjectArylboronic acidsen_US
dc.titleRhodium(I)-catalyzed CO-gas-free arylative dual-carbonylation of alkynes with arylboronic acids via the formyl C-H activation of formaldehydeen_US
dc.typeArticleen_US
dc.institutionauthorArtok, Levent-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume53en_US
dc.identifier.issue18en_US
dc.identifier.startpage3372en_US
dc.identifier.endpage3382en_US
dc.identifier.wosWOS:000642292100001en_US
dc.identifier.scopus2-s2.0-85104947445en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1055/a-1468-8377-
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ3-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.languageiso639-1en-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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