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dc.contributor.advisorÖzdemir, Ekremen
dc.contributor.authorToprak, Görkem-
dc.descriptionThesis (Master)--Izmir Institute of Technology, Chemical Engineering, Izmir, 2013en
dc.descriptionIncludes bibliographical references (leaves: 119-125)en
dc.descriptionText in English; Abstract: Turkish and Englishen
dc.descriptionxv, 122 leavesen
dc.descriptionFull text release delayed at author's request until 2015.07.26en
dc.description.abstractCalcium carbonate (CaCO3) has been used as filling material in various industries such as paint, paper, and polymeric materials. Using filling materials will enhance some of the physical properties of the composite material and decrease the product costs. Especially, the physical properties of the composite materials were enhanced significantly when the CaCO3 is used in nano sizes. CaCO3 can be produced from natural sources by crushing, grinding, and sieving processes, however, calcite obtained from the natural sources are usually in micron sizes and they are not in the desired quality and purity. Here, it was proposed that the dissolution rate of CO2 is the limiting step in CaCO3 crystallization and a small penetration method was developed for the limited dissolution of CO2 in the Ca(OH)2 solution. When Ca(OH)2 was added into the 10 mM CaCO3, zeta potential values of CaCO3 particles were increased from negative to positive value indicating that CaCO3 particles were stabilized in the presence of Ca(OH)2 solution. Rice-like CaCO3 particles were synthesized at the very early stage of crystallization. When crystallization progresses, the high energetic end sites started to dissolve, and the dissolution was progressed through the inside of the particles resulting in hollow calcite particles. BET surface area of hollow calcite particles was found to be 14.75 m2/g. Different parameters such as Ca(OH)2 flow rate, CO2 flow rate, Ca(OH)2 concentration, pipe diameter etc. were studied. Calcite particles in nano sizes, homogeneous size distribution, hollow shapes, and different morphologies were achieved to be produced.en
dc.publisherIzmir Institute of Technologyen
dc.subject.lcshCalcium carbonateen
dc.subject.lcshCalcium hydroxideen
dc.titleProduction of nano CaCo3 in bench scale by small penetration theoryen_US
dc.typeMaster Thesisen_US
dc.institutionauthorToprak, Görkem-
dc.departmentThesis (Master)--İzmir Institute of Technology, Chemical Engineeringen_US
item.openairetypeMaster Thesis-
item.fulltextWith Fulltext-
Appears in Collections:Master Degree / Yüksek Lisans Tezleri
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