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https://hdl.handle.net/11147/3523
Title: | Synthesis, Characterization and Computational Studies of Oxomolybdenum Compounds With Nitrogen Donor Ligands |
Authors: | Kıyak, Harika |
Advisors: | Topaloğlu Sözüer, Işıl |
Publisher: | Izmir Institute of Technology |
Abstract: | In the first part of the project, the reactions of the solvent-stabilized compound [MoO2Cl2(THF)2] with varios phenylenediamine and some napthalenediamin derivatives in THF at room temperature were investigated. These reactions yielded mononuclear and dinuclear compounds of the type [MoO2Cl2L] and [Mo2O3(.2- O)Cl4(L)2] respectively. In the second part, the reactions of [Mo2O3Cl4(DMF)4] with phenylenediamine and napthalenediamin derivatives were studied under similar conditions and Mo-O-Mo bridged dinuclear oxomolybdenum compounds of the type [Mo2O3(.2-O)Cl4(L)] were obtained. The new compounds were comparatively examined by elemental analysis, FTIR, 1H-NMR and 13C-NMR techniques. In addition, quantum chemical calculations including semi empirical PM3 and DFT methods were carried out to discuss the stability and geometry of the compounds. |
Description: | Thesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2010 Includes bibliographical references (leaves: 50-57) Text in English; Abstract: Turkish and English xii, 153 leaves |
URI: | http://hdl.handle.net/11147/3523 |
Appears in Collections: | Master Degree / Yüksek Lisans Tezleri |
Files in This Item:
File | Description | Size | Format | |
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T000827.pdf | MasterThesis | 3.01 MB | Adobe PDF | ![]() View/Open |
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