Please use this identifier to cite or link to this item:
https://hdl.handle.net/11147/3523
Title: | Synthesis, characterization and computational studies of oxomolybdenum compounds with nitrogen donor ligands | Authors: | Kıyak, Harika | Advisors: | Topaloğlu Sözüer, Işıl | Publisher: | Izmir Institute of Technology | Abstract: | In the first part of the project, the reactions of the solvent-stabilized compound [MoO2Cl2(THF)2] with varios phenylenediamine and some napthalenediamin derivatives in THF at room temperature were investigated. These reactions yielded mononuclear and dinuclear compounds of the type [MoO2Cl2L] and [Mo2O3(.2- O)Cl4(L)2] respectively. In the second part, the reactions of [Mo2O3Cl4(DMF)4] with phenylenediamine and napthalenediamin derivatives were studied under similar conditions and Mo-O-Mo bridged dinuclear oxomolybdenum compounds of the type [Mo2O3(.2-O)Cl4(L)] were obtained. The new compounds were comparatively examined by elemental analysis, FTIR, 1H-NMR and 13C-NMR techniques. In addition, quantum chemical calculations including semi empirical PM3 and DFT methods were carried out to discuss the stability and geometry of the compounds. | Description: | Thesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2010 Includes bibliographical references (leaves: 50-57) Text in English; Abstract: Turkish and English xii, 153 leaves |
URI: | http://hdl.handle.net/11147/3523 |
Appears in Collections: | Master Degree / Yüksek Lisans Tezleri |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
T000827.pdf | MasterThesis | 3.01 MB | Adobe PDF | View/Open |
CORE Recommender
Page view(s)
108
checked on Nov 11, 2024
Download(s)
146
checked on Nov 11, 2024
Google ScholarTM
Check
Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.