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https://hdl.handle.net/11147/3370
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DC Field | Value | Language |
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dc.contributor.advisor | Topaloğlu Sözüer, Işıl | en |
dc.contributor.author | Günyar, Alev | - |
dc.date.accessioned | 2014-07-22T13:51:24Z | - |
dc.date.available | 2014-07-22T13:51:24Z | - |
dc.date.issued | 2004 | en |
dc.identifier.uri | http://hdl.handle.net/11147/3370 | - |
dc.description | Thesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2004 | en |
dc.description | Includes bibliographical references (leaves: 50) | en |
dc.description | Text in English; Abstract: Turkish and English | en |
dc.description | xii, 56 leaves | en |
dc.description.abstract | Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimetylpyrazol-1-yl)borate] with p-functionalized anilines[NH2C6H4R] ( R = OMe, OEt, OPr, NO2) in the presence of Et3N under nitrogen, in toluene solution, afforded the novel oxo bridged oxo(arylimido) molybdenum(V) compounds [MoTp*(O)Cl](m-O)[MoTp*(Cl)(ºNC6H4R)] ( R = OMe, OEt, OPr, NO2). Under same conditions, the reaction with aniline produced oxo bridged oxomolybdenum (V) compound, [MoTp*OCl]2(m-O). The new compounds were characterized by FT-IR, FAB-Mass, and 1H-NMRspectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](mO)[MoTp*(Cl)(ºNC6H4OMe)]was carried out to confirm that there is a Mo-O-Mobridge and a near linear arylimido group in the structure. | en |
dc.language.iso | en | en_US |
dc.publisher | Izmir Institute of Technology | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject.lcc | QD181.B1 .G57 2004 | en |
dc.subject.lcsh | Borates | en |
dc.subject.lcsh | Scorpionates | en |
dc.title | Oxo-Imido molybdenum tripyrazolyl borate complexes | en_US |
dc.type | Master Thesis | en_US |
dc.institutionauthor | Günyar, Alev | - |
dc.department | Thesis (Master)--İzmir Institute of Technology, Chemistry | en_US |
dc.relation.publicationcategory | Tez | en_US |
item.grantfulltext | open | - |
item.openairetype | Master Thesis | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
Appears in Collections: | Master Degree / Yüksek Lisans Tezleri |
Files in This Item:
File | Description | Size | Format | |
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T000464.pdf | MasterThesis | 5.82 MB | Adobe PDF | View/Open |
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