Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/3370
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dc.contributor.advisorTopaloğlu Sözüer, Işılen
dc.contributor.authorGünyar, Alev-
dc.date.accessioned2014-07-22T13:51:24Z-
dc.date.available2014-07-22T13:51:24Z-
dc.date.issued2004en
dc.identifier.urihttp://hdl.handle.net/11147/3370-
dc.descriptionThesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2004en
dc.descriptionIncludes bibliographical references (leaves: 50)en
dc.descriptionText in English; Abstract: Turkish and Englishen
dc.descriptionxii, 56 leavesen
dc.description.abstractReaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimetylpyrazol-1-yl)borate] with p-functionalized anilines[NH2C6H4R] ( R = OMe, OEt, OPr, NO2) in the presence of Et3N under nitrogen, in toluene solution, afforded the novel oxo bridged oxo(arylimido) molybdenum(V) compounds [MoTp*(O)Cl](m-O)[MoTp*(Cl)(ºNC6H4R)] ( R = OMe, OEt, OPr, NO2). Under same conditions, the reaction with aniline produced oxo bridged oxomolybdenum (V) compound, [MoTp*OCl]2(m-O). The new compounds were characterized by FT-IR, FAB-Mass, and 1H-NMRspectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](mO)[MoTp*(Cl)(ºNC6H4OMe)]was carried out to confirm that there is a Mo-O-Mobridge and a near linear arylimido group in the structure.en
dc.language.isoenen_US
dc.publisherIzmir Institute of Technologyen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject.lccQD181.B1 .G57 2004en
dc.subject.lcshBoratesen
dc.subject.lcshScorpionatesen
dc.titleOxo-Imido molybdenum tripyrazolyl borate complexesen_US
dc.typeMaster Thesisen_US
dc.institutionauthorGünyar, Alev-
dc.departmentThesis (Master)--İzmir Institute of Technology, Chemistryen_US
dc.relation.publicationcategoryTezen_US
item.grantfulltextopen-
item.openairetypeMaster Thesis-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.fulltextWith Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
Appears in Collections:Master Degree / Yüksek Lisans Tezleri
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