Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2495
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSeyhan, Abdullah Tuğrul-
dc.contributor.authorDe La Vega, Alejandra-
dc.contributor.authorTanoğlu, Metin-
dc.contributor.authorSchulte, Karl-
dc.date.accessioned2016-11-22T12:00:38Z
dc.date.available2016-11-22T12:00:38Z
dc.date.issued2009-08
dc.identifier.citationSeyhan, A.T., De La Vega, A., Tanoğlu, M., and Schulte, K. (2009). Thermal curing behavior of MWCNT modified vinyl ester-Polyester resin suspensions prepared with 3-roll milling technique. Journal of Polymer Science, Part B: Polymer Physics, 47(15), 1511-1522. doi:10.1002/polb.21755en_US
dc.identifier.issn0887-6266
dc.identifier.issn0887-6266-
dc.identifier.issn1099-0488-
dc.identifier.urihttp://dx.doi.org/10.1002/polb.21755
dc.identifier.urihttp://hdl.handle.net/11147/2495
dc.description.abstractThis study aims to investigate the curing behavior of a vinyl ester-polyester resin suspensions containing 0.3 wt % of multiwalled carbon nanotubes with and without amine functional groups (MWCNTs and MWCNT-NH2). For this purpose, various analytical techniques, including Differential Scanning Calorimetry (DSC), Fourier infrared spectroscopy (FTIR), Raman Spectroscopy, and Thermo Gravimetric Analyzer (TGA) were conducted. The resin suspensions with carbon nanotubes (CNTs) were prepared via 3-roll milling technique. DSC measurements showed that resin suspensions containing CNTs exhibited higher heat of cure (Q), besides lower activation energy (Ea) when compared with neat resin. For the sake of simplicity of interpretation, FTIR investigations were performed on neat vinyl ester resin suspensions containing the same amount of CNTs as resin. As a result, the individual fractional conversion rates of styrene and vinyl ester were interestingly found to be altered dependent on MWCNTs and MWCNT-NH2. The findings obtained from RS measurements of the cured samples are highly proportional to those obtained from FTIR measurements. TGA measurements revealed that CNT modified nanocomposites have higher activation energy of degradation (Ed) compared with the cured polymer. The findings obtained revealed that CNTs with and without amine functional groups alter overall thermal curing response of the surrounding matrix resin, which may probably impart distinctive characteristics to mechanical behavior of the corresponding nanocomposites achieved.en_US
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Inc.en_US
dc.relation.ispartofJournal of Polymer Science, Part B: Polymer Physicsen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectFTIRen_US
dc.subjectMultiwalled carbon nanotubesen_US
dc.subjectRadical polymerizationen_US
dc.subjectRaman spectroscopyen_US
dc.subjectDifferential scanning calorimeteren_US
dc.subjectThermal gravimetric analysisen_US
dc.titleThermal curing behavior of MWCNT modified vinyl ester-Polyester resin suspensions prepared with 3-roll milling techniqueen_US
dc.typeArticleen_US
dc.authoridTR30837en_US
dc.institutionauthorTanoğlu, Metin-
dc.departmentİzmir Institute of Technology. Mechanical Engineeringen_US
dc.identifier.volume47en_US
dc.identifier.issue15en_US
dc.identifier.startpage1511en_US
dc.identifier.endpage1522en_US
dc.identifier.wosWOS:000268032200008en_US
dc.identifier.scopus2-s2.0-67849116820en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1002/polb.21755-
dc.relation.doi10.1002/polb.21755en_US
dc.coverage.doi10.1002/polb.21755en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ1-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeArticle-
item.fulltextWith Fulltext-
crisitem.author.dept03.10. Department of Mechanical Engineering-
Appears in Collections:Mechanical Engineering / Makina Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Files in This Item:
File Description SizeFormat 
2495.pdfMakale390.87 kBAdobe PDFThumbnail
View/Open
Show simple item record



CORE Recommender

SCOPUSTM   
Citations

19
checked on Jun 21, 2024

WEB OF SCIENCETM
Citations

17
checked on Jun 21, 2024

Page view(s)

158
checked on Jun 24, 2024

Download(s)

244
checked on Jun 24, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.