Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
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Browsing Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği by Language "eng"
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Article Citation - WoS: 17Citation - Scopus: 18Development of an Ionic Liquid Based Method for the Preparation of Albumin Nanoparticles(John Wiley and Sons Inc., 2018-09) Demirkurt, Begüm; Akdoğan, Yaşar; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyAlbumin based nanocarriers have been widely used in drug delivery studies. Here, we developed a water-in-ionic liquid (IL) emulsion-like method to prepare bovine serum albumin (BSA) nanoparticles as alternative to the traditional organic solvents containing techniques. Conformational changes of albumin induced by the imidazolium based ILs at the water-IL interface triggers the BSA nanoparticle formation. The albumin nanoparticle formation are dependent on the experimental parameters and the hydophobicity of the IL. At pH 9.0, using 1.3%wt of BSA in water/1-butyl-3-methyl imidazolium tetrafluoroborate (BmimBF4) (50/50 mol%) and TX-100/butanol surfactant mixture yields uniformly distributed 200 nm average sized BSA nanoparticles. Different than BmimBF4, using a more hydrophilic IL, EmimBF4 yielded albumin aggregates. Instead, using a more hydrophobic IL, HmimBF4 produced albumin nanoparticles but a non-uniform size distribution was obtained. These results indicate that the ionic liquids called green and designer solvents can be also used to synthesize albumin nanoparticles.Article Citation - WoS: 84Citation - Scopus: 85A Review on Halide Perovskites as Color Conversion Layers in White Light Emitting Diode Applications(John Wiley and Sons Inc., 2018-07) Güner, Tuğrul; Demir, Mustafa Muammer; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyIn the last decade, halide perovskites have attracted great interest due to many reasons, including their low cost, solution-processability, superior PL properties, broad range of color tunability, color purity, and defect tolerance, among others. They are in increasing demand for a wide range of applications, such as solar cells, light emitting diodes (LEDs), white LEDs (WLED), and lasers. Yellow phosphors have been heavily employed in solid-state lighting, since its illumination by blue yields white light with various optical features, such as high/low CRI, CCT, and luminous efficiency. However, phosphors as pigments are seldom found and are costly material. In this sense, halide perovskites may offer a promising alternative to phosphors for future solid-state lighting. In this study, the synthesis and optical properties of halide perovskites, as well as their application in WLED as a conversion layer are investigated.Article A Study on Recyclability of Alsi7mg0.3 Machining Waste(2023) Gökelma, Mertol; Önen Tüzgel, Rabia; Kaya, Ahmet Yiğit; Özaydın, Onur; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyAluminium products are widely used in the automotive industry. One of the important aluminium products in the automotive is wheel production. Turkish wheel production is expected to reach 360000 tons in 2025. The wheels are produced by Low-Pressure Die Casting at the first stage and the machining process in CNC machines is used to create the final form. A significant amount of machining waste (swarf, turnings, and chips) is created during the machining and the importance of secondary aluminium has been increasing due to environmental and economic concerns. This study focuses on the recycling of AlSi7Mg0.3 cast alloy machining waste. The turnings were sorted into two size fractions and remelted separately under a salt flux in a resistance heating furnace. Two different salt mixtures with different melting points and different salt factors were studied in this work. Metal yield and coagulation yield after remelting were discussed.Article Citation - WoS: 7Citation - Scopus: 8Synthesis and Characterization of Novel High Temperature Structural Adhesives Based on Nadic End Capped Mda-Btda Copolyimide(IOP Publishing Ltd., 2018-10) Acar, Oktay; Varış, Serhat; Işık, Tuğba; Tirkeş, Seha; Demir, Mustafa Muammer; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyA series of novel copolyimide structural adhesives were synthesized using 4,4′-diaminodiphenylmethane (MDA), 3,4′-oxydianiline (ODA) and 3,3′,4,4′-benzophenonetetracarboxylic acid dianhydride (BTDA) as co-monomers, and nadic anhydride as an end cap reagent. The adhesives with different MDA and ODA contents were examined in terms of their structure, thermal stability, mechanical properties, and adhesive performance. They have glass transition temperatures (T g) about 400 °C, with thermal stability up to 500 °C. The effect of diamine monomer compositions on adhesion performance and processability of the copolyimides were studied. The copolyimides exhibited adhesion strength up to 16.3 MPa at room temperature. Nadic end capped MDA-BTDA-ODA copolyimide resins gained adjustable and controllable processability with the addition of ether bridged aromatic segments. The copolyimide adhesive with equimolar composition of MDA:ODA is distinguished form the both commercial PMR-15 and LARC RP-46 polyimides in terms of its better processability and mechanical performance.