Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2949
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dc.contributor.advisorÇakicioğlu Özkan, Seher Fehimeen
dc.contributor.authorGüneş Yerkesikli, Alev-
dc.date.accessioned2014-07-22T13:48:39Z-
dc.date.available2014-07-22T13:48:39Z-
dc.date.issued2013en
dc.identifier.urihttp://hdl.handle.net/11147/2949-
dc.descriptionThesis (Doctoral)--Izmir Institute of Technology, Chemical Engineering, Izmir, 2013en
dc.descriptionIncludes bibliographical references (leaves: 90-96)en
dc.descriptionText in English; Abstract: Turkish and Englishen
dc.descriptionx, 96 leavesen
dc.description.abstractSynthetic gas produced from steam methane reforming (SMR off -gas) is a mixture of H2, CO, CO2, and CH4 can be used in fuel cell after purification. In this study adsorption as a purification tool was used to obtain high H2 content of gas mixture from SMR off gas. Zeolites and metal organic framework were used as an adsorbent. CO2 equilibrium studies on K rich NaX zeolites, prepared with ultrasonic and traditional methods, and metal organic framework MIL53 (Al) shows high adsorption on zeolites than MIL53(Al) up to 1 atm. K rich zeolites give lower adsorption than NaX zeolite. Adsorption isotherms obtained for MIL53 (Al) is linear ( favorable for zeolites). This makes MIL53(Al) is an promising adsorbent for high pressure application. Adsorption equilibrium at 5 atm shows that NaX zeolite is good adsorbent for the SMR off gas with the following orders: CO2>CH4>CO> H2. Kinetics of SMR off gas in MIL 53 (Al) were studied by using Zero Length Column (ZLC) method. The results show that the calculated diffusivities are strongly dependent on temperature but weakly dependent on purge flow rate. The study reveals that transport is controlled by intracrystalline diffusion. The activation energy on diffusion are nearly same (about 41 kJ/mol) and not change with respect to kinetic diameter of SMR off gases. Heat of SMR off gas adsorption on MIL53(Al) obtained from Henry’s constant shows that adsorption is exothermic. The study shows that the ZLC method is an effective tool to investigate the diffusion kinetics of SMR off-gas gases in MIL53(Al).en
dc.language.isoenen_US
dc.publisherIzmir Institute of Technologyen
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject.lcshGases--Absorption and adsorptionen
dc.titleAdsorption of reformer off-gas on NaX zeolite and metal organic framework (mil53(AI)): Equilibria and kineticsen_US
dc.typeDoctoral Thesisen_US
dc.institutionauthorGüneş Yerkesikli, Alev-
dc.departmentIzmir Institute of Technology. Chemical Engineeringen
dc.relation.publicationcategoryTezen_US
item.openairetypeDoctoral Thesis-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
Appears in Collections:Phd Degree / Doktora
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