PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7645
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Browsing PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection by Language "eng"
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Article Citation - WoS: 19Citation - Scopus: 29Modeling of an Activated Sludge Process for Effluent Prediction—a Comparative Study Using Anfis and Glm Regression(Springer Verlag, 2018-09) Araromi, Dauda Olurotimi; Majekodunmi, Olukayode Titus; Adeniran, Jamiu Adetayo; Salawudeen, Taofeeq OlalekanIn this paper, nonlinear system identification of the activated sludge process in an industrial wastewater treatment plant was completed using adaptive neuro-fuzzy inference system (ANFIS) and generalized linear model (GLM) regression. Predictive models of the effluent chemical and 5-day biochemical oxygen demands were developed from measured past inputs and outputs. From a set of candidates, least absolute shrinkage and selection operator (LASSO), and a fuzzy brute-force search were utilized in selecting the best combination of regressors for the GLMs and ANFIS models respectively. Root mean square error (RMSE) and Pearson’s correlation coefficient (R-value) served as metrics in assessing the predicting performance of the models. Contrasted with the GLM predictions, the obtained modeling results show that the ANFIS models provide better predictions of the studied effluent variables. The results of the empirical search for the dominant regressors indicate the models have an enormous potential in the estimation of the time lag before a desired effluent quality can be realized, and preempting process disturbances. Hence, the models can be used in developing a software tool that will facilitate the effective management of the treatment operation.Article Citation - WoS: 14Citation - Scopus: 12Phase Behavior of Dspc/Peg40st Mixtures at Higher Emulsifier Contents(Elsevier Ltd., 2018-11) Kılıç, Sevgi; Bölükçü, Elif ŞenizPhase behaviors of 1,2-Distearoyl-sn-glycero-3-phosphocholine (DSPC) and polyoxyethylene(40)stearate (PEG40St) were investigated with Langmuir monolayer isotherms and Brewster angle microscopy (BAM) imaging at DSPC/PEG40St molar ratios ranging from 9:1 to 5:5. Two plateaus were found in the Langmuir isotherms which were relatively shorter for the 9:1 mixture and extended significantly by increasing the PEG40St content, indicating that the PEG40St squeezed out whereas more emulsifier retained in the monolayer at higher PEG40St contents. A strong hysteresis was observed when the mixed monolayers were subjected to compression-expansion cycles. The degree of hysteresis for the first cycles also increased with increasing PEG40St content in the monolayer. Gray scale intensities in the Brewster angle microscopy images were determined for pure DSPC and pure PEG40St and a scale was established to better interpret the morphologies for the mixtures. Bud and vessels formed during the PEG40St squeezed out upon compression. Upon expansion, PEG40St and DSPC is reappeared on the monolayer. When considered BAM images together with the Langmuir isotherm, PEG40St molecules were found to be well distributed within the DSPC molecules at lower DSPC/PEG40St mole ratios and mostly phase separated at higher mole ratios. It was concluded that higher PEG40St content would be advantageous for the design of an efficient and cheaper ultrasound contrast agents.Article Citation - WoS: 90Citation - Scopus: 94Source Apportionment and Carcinogenic Risk Assessment of Passive Air Sampler-Derived Pahs and Pcbs in a Heavily Industrialized Region(Elsevier Ltd., 2018-08) Çetin, Banu; Yurdakul, Sema; Güngörmüş, Elif; Öztürk, Fatma; Sofuoğlu, Sait CemilCancer has become the primary reason of deaths in Dilovasi probably due to its location with unique topography under the influence of heavy industrialization and traffic. In this study, possible sources and carcinogenic health risks of PAHs and PCBs were investigated in Dilovasi region by Positive Matrix Factorization (PMF) and the USEPA approach, respectively. PAHs and PCBs were measured monthly for a whole year at 23 sampling sites using PUF disk passive samplers. Average ambient air concentrations were found as 285 ± 431 ng/m 3 and 4152 ± 6072 pg/m 3 , for Σ 15 PAH and Σ 41 PCB, respectively. PAH concentrations increased with decreasing temperature especially at urban sites, indicating the impact of residential heating in addition to industrial activities and traffic. On the other hand, PCB concentrations mostly increased with temperature probably due to enhanced volatilization from their sources. Possible sources of PAHs were found as emissions of diesel and gasoline vehicles, biomass and coal combustion, iron and steel industry, and unburned petroleum/petroleum products, whereas iron-steel production, coal and biomass burning, technical PCB mixtures, and industrial emissions were identified for PCBs. The mean carcinogenic risk associated with inhalation exposure to PAHs and PCBs were estimated to be >10 −6 and >10 −5 , respectively, at all sampling points, while the 95th percentile was >10 −5 at 15 of 23 and >10 −4 at 8 of 23 sampling locations, respectively. Probabilistic assessment showed, especially for PCBs, that a majority of Dilovasi population face significant health risks. The higher risks due to PCBs further indicated that PCBs and possibly other pollutants originating from the same sources such as PBDEs and PCNs may be an important issue for the region.