Environmental Engineering / Çevre Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4321
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Browsing Environmental Engineering / Çevre Mühendisliği by Journal "Atmospheric Pollution Research"
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Article Citation - WoS: 5Citation - Scopus: 7Bleach-Containing Automatic Toilet-Bowl Cleaners as Sources of Vocs, Associated Indoor Air Concentrations and Carcinogenic Risk(Turkish National Committee for Air Pollution Research (TUNCAP), 2020) Ayrı, İlknur; Genişoğlu, Mesut; Gaygısız, Handan; Sofuoğlu, Aysun; Sofuoğlu, Sait Cemil; 03.02. Department of Chemical Engineering; 03.07. Department of Environmental Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyHousehold cleaning products are sources of volatile organic compounds (VOCs). Bleach containing products are a special case because reactions occur between chloride and their organic content such as surfactants, perfumes, etc., generating VOCs. This study aimed to determine concentration of 13 VOCs in bleach-containing automatic toilet cleaners, to estimate their indoor air concentrations and associated exposure and health risk levels. Experiments with products purchased from supermarkets were conducted in 20-mL headspace vials by placing 1 g of sample with and without water. Solid-phase micro extraction with a DVB/CAR/PDMS fiber assembly was used for adsorption of VOCs from the headspace, and analyzed using a GC-MS. The median carbon tetrachloride and chloroform concentrations of the studied products ranged from 5.03 × 10?3 to 2.37 × 10?2 ?g/g and 2.53 × 10?2 to 2.37 ?g/g, respectively. The modeled 95th percentile indoor air concentrations in a 1.6 m3 bathroom with no ventilation were estimated to be 1 and 20 ?g/m3 for carbon tetrachloride and chloroform, respectively. The 95th percentile carcinogenic risk associated even with the use of the highest content product, 3.72 × 10?7 and 8.62 × 10?7 for carbon tetrachloride and chloroform respectively, were below the acceptable risk. In conclusion, automatic toilet-bowl cleaners were found to be sources of VOCs, but their emission potentials are not high to cause considerable indoor air concentrations over their suggested product lifetime. In turn, carcinogenic risks associated with inhalation exposure are below the de Minimis risk level of 10?6. © 2020Article Citation - WoS: 4Citation - Scopus: 4Radiological Modeling of the Impacts of the Chernobyl Nuclear Power Plant Accident on Turkey and Southwest Asia(Elsevier, 2022-02) Bilgiç, Efem; Gündüz, Orhan; 03.07. Department of Environmental Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyMany studies investigated the impacts of the Chernobyl Nuclear Power Plant accident on Europe. However, majority of these have spatially excluded the highly populated southeast region of Chernobyl, including countries such as Turkey, Armenia, Georgia and Iran. In this study, a comprehensive environmental and radiological analysis were conducted particularly for this region. For this purpose, atmospheric dispersion and ground deposition of radionuclides were estimated using a Lagrangian particle dispersion model, FLEXPART. Totally, six simulations were conducted and model results were validated with measurements from Europe and Turkey. Furthermore, total effective dose equivalent (TEDE) values were estimated for adults and infants using the most current dose conversion factors of ICRP. Highest deposition of 137Cs were found in around Eastern Black Sea areas (10–40 kBq/m2). Similar values were found in some locations of Armenia and Azerbaijan under some scenarios, but country averages of 137Cs deposition were lower than 10 kBq/m2 for both countries. No significant depositions were found in southwest Iran, but relatively higher depositions (2–10 kBq/m2) of 137Cs were estimated along the Turkish border. Although there were slightly higher values in northern areas of Syria, Iraq, Lebanon and Cyprus, 137Cs depositions were mostly less than 2 kBq/m2. The 1-year TEDE value was calculated less than 1 mSv throughout the model domain except for some regions of eastern Black Sea. Highest values in lifetime dose values were calculated along the Black Sea coasts of Turkey and Georgia. Overall, infants were affected more from ionizing radiation compared to adults in this region.