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dc.contributor.authorKu?, M.
dc.contributor.authorArtok, Ö.A.
dc.contributor.authorZiyanak, F.
dc.contributor.authorArtok, L.
dc.date.accessioned2021-02-12T18:43:50Z
dc.date.available2021-02-12T18:43:50Z
dc.date.issued2008
dc.identifier.issn0936-5214
dc.identifier.urihttps://doi.org/10.1055/3-2008-1078047
dc.identifier.urihttps://hdl.handle.net/11147/9775
dc.description.abstractThe Rh-catalyzed reaction of arylboronic acids with internal alkynes under a CO atmosphere in the presence of an acid additive afforded ?,?-unsaturated ketones as the major products. Hydroacylation of internal alkynes, except in the case of diaryl acetylenes, proceeded in syn fashion, yielding the E-configured isomer. A mixture of E- and Z-isomers was obtained with diphenyl acetylene. Reactions were also highly regioselective for various nonsymmetric alkynes.en_US
dc.language.isoengen_US
dc.relation.isversionof10.1055/3-2008-1078047en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAlkynesen_US
dc.subjectBoronen_US
dc.subjectCarbonylationen_US
dc.subjectEnonesen_US
dc.subjectRhodiumen_US
dc.titleSynthesis of ?,?-unsaturated ketones by rhodium-catalyzed carbonylative arylation of internal alkynes with arylboronic acidsen_US
dc.typearticleen_US
dc.typearticleen_US
dc.relation.journalSynletten_US
dc.contributor.departmentIzmir Isntitute of Technologyen_US
dc.identifier.issue17en_US
dc.identifier.startpage2587en_US
dc.identifier.endpage2592en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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