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dc.contributor.authorAlp, Burcu
dc.contributor.authorCesur, Serap
dc.date.accessioned2017-03-28T07:15:37Z
dc.date.available2017-03-28T07:15:37Z
dc.date.issued2013-10
dc.identifier.citationAlp, B., and Cesur, S. (2013). Isothermal crystallization kinetics and mechanical properties of polycaprolactone composites with zinc oxide, oleic acid, and glycerol monooleate. Journal of Applied Polymer Science, 130(2), 1259-1275. doi:10.1002/app.39217en_US
dc.identifier.issn0021-8995
dc.identifier.urihttps://doi.org/10.1002/app.39217
dc.identifier.urihttp://hdl.handle.net/11147/5150
dc.description.abstractThe isothermal crystallization and mechanical behavior of polycaprolactone (PCL) with zinc oxide (ZnO) with oleic acid and glycerol monooleate (GMO) were studied. Theoretical melting points calculated by the Flory-Huggins and Thompson-Gibbs models were thoroughly compared with differential scanning calorimetry experimental observations. The isothermal crystallization kinetic parameters by Avrami analysis showed that crystallization was controlled by nucleation, crystal growth was spherical, and the nucleation type changed between thermal and athermal nucleation. X-ray diffraction showed that when the additives were used together both the crystal thickness and the degree of crystallinity increased. A multiple-response regression analysis was made with the ZnO, oleic acid, and GMO concentrations as variables and the crystallinity as output. Interaction parameters by the Pukanzky model were calculated from the tensile strength at the yield point and indicated that the addition of oleic acid or GMO improved the interface between the ZnO particles and PCL.en_US
dc.description.sponsorshipTUBITAK-110M157; Ege University Scientific Research Project Fund (BAP 09/MUH/093)en_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.isversionof10.1002/app.39217en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectZinc oxideen_US
dc.subjectCompositesen_US
dc.subjectCrystallizationen_US
dc.subjectKineticsen_US
dc.subjectMechanical propertiesen_US
dc.titleIsothermal crystallization kinetics and mechanical properties of polycaprolactone composites with zinc oxide, oleic acid, and glycerol monooleateen_US
dc.typearticleen_US
dc.contributor.authorIDTR116811en_US
dc.contributor.institutionauthorAlp, Burcu
dc.relation.journalJournal of Applied Polymer Scienceen_US
dc.contributor.departmentIzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume130en_US
dc.identifier.issue2en_US
dc.identifier.startpage1259en_US
dc.identifier.endpage1275en_US
dc.identifier.wosWOS:000322238200064
dc.identifier.scopusSCOPUS:2-s2.0-84880918506
dc.relation.tubitakinfo:eu-repo/grantAgreement/TUBITAK/MAG/110M157en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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