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dc.contributor.authorTıhmınlıoğlu, Funda
dc.contributor.authorDanner, Ronald P.
dc.contributor.authorLützow, Norbert
dc.contributor.authorDuda, John Larry
dc.date.accessioned2016-04-21T11:01:27Z
dc.date.available2016-04-21T11:01:27Z
dc.date.issued2000-09
dc.identifier.citationTıhmınlıoğlu, F., Danner, R. P., Lützow, N., and Duda, J. L. (2000). Solvent diffusion in amorphous polymers: Polyvinyl acetate-toluene system. Journal of Polymer Science, Part B: Polymer Physics, 38(18), 2429-2435. doi:10.1002/1099-0488(20000915)38:18<2429::AID-POLB100>3.0.CO;2-Men_US
dc.identifier.issn0887-6266
dc.identifier.urihttp://doi.org/10.1002/1099-0488(20000915)38:18<2429::AID-POLB100>3.0.CO;2-M
dc.identifier.urihttp://hdl.handle.net/11147/4531
dc.description.abstractIn a previous publication (Tihminlioglu et al., J Polym Sci Part B: Polym Phys 1997, 35, 1279), we presented an extensive analysis of the polyvinyl acetate-toluene system. The inverse gas chromatography (IGC) technique was used to measure phase equilibria and diffusion coefficients above and near the glass-transition temperature of a polymer. At temperatures above the glass transition, the capillary column model developed by Pawlisch et al. (Macromolecules 1987, 20, 1564) was used. For the finite concentration region, the modified model of Tihminlioglu and Danner (J Chromatogr A 1999, 845, 93) was applied. Data obtained with the IGC method were in agreement with data measured with the gravimetric and piezoelectric sorption techniques. In this work, we revisit the partition coefficient issue and provide some new data at lower temperatures. At temperatures near the glass-transition temperature, the modification of the capillary column model proposed by Vrentas et al. (Macromolecules 1993, 26, 6670) was used for the infinite dilution region. The diffusion data correlated well with the Vrentas-Duda free-volume model.en_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.isversionof10.1002/1099-0488(20000915)38:18<2429::AID-POLB100>3.0.CO;2-Men_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPolyvinyl acetatesen_US
dc.subjectAmorphous materialsen_US
dc.subjectCorrelation methodsen_US
dc.subjectDiffusionen_US
dc.subjectGas chromatographyen_US
dc.titleSolvent diffusion in amorphous polymers: Polyvinyl acetate-toluene systemen_US
dc.typearticleen_US
dc.contributor.authorIDTR1143en_US
dc.contributor.iztechauthorTıhmınlıoğlu, Funda
dc.relation.journalJournal of Polymer Science, Part B: Polymer Physicsen_US
dc.contributor.departmentIzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume38en_US
dc.identifier.issue18en_US
dc.identifier.startpage2429en_US
dc.identifier.endpage2435en_US
dc.identifier.wosWOS:000089004200010
dc.identifier.scopusSCOPUS:2-s2.0-0034272736
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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