Gerçek Zamanlı Erişim Haritası
Hydrothermal synthesis and characterization of a novel supramolecular hybrid based on Keggin and Cu(I) complex
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A novel inorganic-organic hybrid molecule, [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O (1), has been hydrothermally synthesized and characterized by IR spectra, TG and single crystal X-ray diffraction analyses. Structural analysis reveals that the novel compound 1 composed of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.