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Synthesis and characterization of a new mono-molybdenated metallo-ligand [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(OC 6H4PPh2-p)]
(Taylor & Francis, 1999)
The "metallo-ligands" can be considered effectively as a modified triphenylphosphine ligand, and used to generate novel transtion metal complexes in which electron-transfer and magnetism is embedded within the stable ligand ...
Synthesis and characterization of amido and amido(monoalkylamido)nitrosyl-[tris(3,5-dimethylpyrazolyl)borato]molybdenum complexes
(Taylor & Francis, 1997)
The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl 2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH 2)(NHR)] (R = Me, ...
Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(η5-C2B 9H10Me2)]
(Taylor & Francis, 1996)
In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was ...
