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Rhodium- and palladium-catalyzed 1,5-substitution reactions of 2-En-4-yne acetates and carbonates with organoboronic acids

Üçüncü, Muhammed; Karakuş, Erman; Kuş, Melih; Akpınar, Gürkan Eray; Aksın Artok, Özge; Krause, Norbert; Karaca, Sıla; Nuran, Elmacı; Artok, Levent (American Chemical Society, 2011-08)

Two methods involving the rhodium-catalyzed reaction of 2-en-4-yne acetates and the palladium-catalyzed reaction of 2-en-4-yne carbonates with organoboronic acids were investigated; both afforded exclusively the (E)-configured ...