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dc.contributor.authorArkış, Esen
dc.contributor.authorBalköse, Devrim
dc.date.accessioned2016-07-22T08:41:25Z
dc.date.available2016-07-22T08:41:25Z
dc.date.issued2005-04
dc.identifier.citationArkış, E., and Balköse, D. (2005). Thermal stabilisation of poly(vinyl chloride) by organotin compounds. Polymer Degradation and Stability, 88(1), 46-51. doi:10.1016/j.polymdegradstab.2004.02.021en_US
dc.identifier.issn0141-3910
dc.identifier.urihttps://doi.org/10.1016/j.polymdegradstab.2004.02.021
dc.identifier.urihttp://hdl.handle.net/11147/1968
dc.description.abstractThe effect of LSN 117 (dioctyl tin bis isooctyl thioglycollate, an organotin compound) on the heat stability of plasticised PVC was investigated in this study. The organotin stabiliser had carbonyl and carboxylate groups and PVC contained traces of Fe, Zn, Ca, Cu and Sn. The heat stability of the films were tested at 140 °C and 160 °C or 180 °C by heating in an air circulation oven up to 2 h and by measuring HCl evolved using a Metrohm 763 PVC thermomat and by thermogravimetric analysis. The onset of HCl evolution was at 14.3 and 2.5 h at 140 °C and 160 °C, respectively, for PVC film without LSN117. On the other hand, the film with LSN117 did not evolve HCl in 30.3 h at 140 °C. HCl started to evolve from the films with LSN 117 in 14.3 h at 160 °C. The TGA curve also indicated PVC film with LSN 117 degraded at higher temperatures than control films. LSN 117 was found to be a good heat stabiliser for plasticised PVC and it did not have any detrimental effect on mechanical properties.en_US
dc.description.sponsorshipEge University Research Fund: No. 98/MÜH/15en_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.relation.isversionof10.1016/j.polymdegradstab.2004.02.021en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectChemical bondsen_US
dc.subjectDehydrochlorinationen_US
dc.subjectDioctyl phthalateen_US
dc.subjectOrganotinen_US
dc.subjectPVC heat stabilizeren_US
dc.titleThermal stabilisation of poly(vinyl chloride) by organotin compoundsen_US
dc.typeconferenceObjecten_US
dc.contributor.institutionauthorArkış, Esen
dc.contributor.institutionauthorBalköse, Devrim
dc.relation.journalPolymer Degradation and Stabilityen_US
dc.contributor.departmentIzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume88en_US
dc.identifier.issue1en_US
dc.identifier.startpage46en_US
dc.identifier.endpage51en_US
dc.identifier.wosWOS:000227570800008
dc.identifier.scopusSCOPUS:2-s2.0-13844266885
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanıen_US


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