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dc.contributor.authorOzguler, Sahika
dc.contributor.authorDiker, Halide
dc.contributor.authorUnluturk, Secil Sevim
dc.contributor.authorOzcelik, Serdar
dc.contributor.authorVarlikli, Canan
dc.date.accessioned2021-02-12T18:47:25Z
dc.date.available2021-02-12T18:47:25Z
dc.date.issued2020
dc.identifier.issn1932-7447
dc.identifier.issn1932-7455
dc.identifier.urihttps://doi.org/10.1021/acs.jpcc.0c02769
dc.identifier.urihttps://hdl.handle.net/11147/10176
dc.descriptionSEVIM UNLUTURK, Secil/0000-0001-8300-3837; Varlikli, Canan/0000-0002-1081-0803en_US
dc.description.abstractGreen light-emitting CdSe@ZnS/ZnS (QD) nano-particles were synthesized; the photophysical and morphological properties of their films, which were prepared by spin coating from six different concentrations, corresponding to absorbance values of 0.6, 1.1, 1.6, 2.1, 2.8, and 4.0, were determined. Increasing the absorbance value from 0.6 to 4.0 did not change the photophysical properties of QD films to a large extent, whereas it resulted in an increment in QD film thickness from 20 to 110 nm. The films were utilized as an emissive layer in QD light-emitting diodes with poly(9-vinylcarbazole) (PVK), PVK:2-(4-biphenyllyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD), and PVK:1,3-bis[(4-tert-butylphenyl)-1,3,4-oxadiazolyl]-phenylene (OXD-7) hole-transport layers (HTLs). The presence of PBD or OXD-7 in PVK reduced the efficiency values but played a positive role in the color purity and efficiency roll off. The maximum color temperature and electroluminescence wavelength shifts obtained with applied potential were 109, 50, and 50 K and 11, 5, and 5 nm for pure-PVK, PVK:PBD, and PVK:OXD-7-based devices, respectively. Hole mobility, capacitance (at 10(3) Hz), and charge-transfer efficiency values were 9.0 x 10(-7), 6.8 x 10(-7), and 4.2 x 10(-7) cm(2) V s(-1), 1.7, 1, and 1 nF, and 6.90%, 15.50%, and 16.10% for pure-PVK, PVK:PBD, and PVK:OXD-7-based devices, respectively. Enhanced color purity and lowered efficiency roll off obtained with PVK:PBD and PVK:OXD-7 HTLs were attributed to decreased capacitance, increased charge-transfer efficiency, and reduced Joule heating.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [115F616]en_US
dc.description.sponsorshipWe acknowledge project support from the Scientific and Technological Research Council of Turkey (TUBITAK) (Project no. 115F616) and thank the Izmir Institute of Technology, The Centre for Materials Research for AFM measurements.en_US
dc.language.isoengen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.isversionof10.1021/acs.jpcc.0c02769en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleReducing the Efficiency Roll Off and Applied Potential-Induced Color Shifts in CdSe@ZnS/ZnS-Based Light-Emitting Diodesen_US
dc.typearticleen_US
dc.typearticleen_US
dc.relation.journalJournal of Physical Chemistry Cen_US
dc.contributor.departmentIzmir Isntitute of Technologyen_US
dc.identifier.volume124en_US
dc.identifier.issue27en_US
dc.identifier.startpage14847en_US
dc.identifier.endpage14854en_US
dc.identifier.wosWOS:000550763500049
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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