Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/5574
Full metadata record
DC FieldValueLanguage
dc.contributor.authorTopuzogulları, Murat-
dc.contributor.authorBulmuş, Volga-
dc.contributor.authorDalgakıran, Eray-
dc.contributor.authorDinçer, Sevil-
dc.date.accessioned2017-05-23T07:54:17Z-
dc.date.available2017-05-23T07:54:17Z-
dc.date.issued2014-01-
dc.identifier.citationTopuzoğulları, M., Bulmuş, V., Dalgakıran, E., and Dinçer, S. (2014). PH- and temperature-responsive amphiphilic diblock copolymers of 4-vinylpyridine and oligoethyleneglycol methacrylate synthesized by RAFT polymerization. Polymer, 55(2), 525-534. doi:10.1016/j.polymer.2013.12.040en_US
dc.identifier.issn0032-3861-
dc.identifier.urihttps://doi.org/10.1016/j.polymer.2013.12.040-
dc.identifier.urihttp://hdl.handle.net/11147/5574-
dc.description.abstractDiblock copolymers of 4-vinylpyridine (4VP) and oligoethyleneglycol methyl ether methacrylate (OEGMA) were synthesized for the first time using RAFT polymerization technique as potential drug delivery systems. Effects of the number of ethylene glycol units in OEGMA, chain length of hydrophobic P4VP block, pH, concentration and temperature on the solution behavior of the copolymers were investigated comprehensively. Copolymer chains formed micelles at pH values higher than 5 whereas unimeric polymers were observed to exist below pH 5, owing to the repulsion between positively charged P4VP blocks. The size of the micelles was dependent on the relative length of blocks, P4VP and POEGMA. Thermo-responsive properties of copolymers were investigated depending on the pH and length of P4VP block. The increase in the length of P4VP block decreased the LCST substantially at pH 7. At pH 3, LCST of copolymers shifted to higher temperatures due to the increased interaction of copolymers with water through positively charged P4VP block.en_US
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (110T570)en_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofPolymeren_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAmphiphilic block copolymersen_US
dc.subjectRAFT polymerizationen_US
dc.subjectStimuli-responsiveen_US
dc.subjectLiving polymerizationen_US
dc.titlePH- and temperature-responsive amphiphilic diblock copolymers of 4-vinylpyridine and oligoethyleneglycol methacrylate synthesized by RAFT polymerizationen_US
dc.typeArticleen_US
dc.authoridTR181383en_US
dc.institutionauthorBulmuş, Volga-
dc.departmentİzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume55en_US
dc.identifier.issue2en_US
dc.identifier.startpage525en_US
dc.identifier.endpage534en_US
dc.identifier.wosWOS:000331154700009en_US
dc.identifier.scopus2-s2.0-84892817368en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.polymer.2013.12.040-
dc.relation.doi10.1016/j.polymer.2013.12.040en_US
dc.coverage.doi10.1016/j.polymer.2013.12.040en_US
dc.identifier.wosqualityQ1-
dc.identifier.scopusqualityQ1-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
crisitem.author.dept03.01. Department of Bioengineering-
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Files in This Item:
File Description SizeFormat 
5574.pdfMakale1.27 MBAdobe PDFThumbnail
View/Open
Show simple item record



CORE Recommender

SCOPUSTM   
Citations

32
checked on Mar 22, 2024

WEB OF SCIENCETM
Citations

32
checked on Mar 27, 2024

Page view(s)

250
checked on Mar 25, 2024

Download(s)

392
checked on Mar 25, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.