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dc.contributor.authorTaç, Doğan
dc.contributor.authorAytaç, İsmet Arınç
dc.contributor.authorKaratavuk, Ali Osman
dc.contributor.authorKuş, Melih
dc.contributor.authorZiyanak, Fırat
dc.contributor.authorArtok, Levent
dc.date.accessioned2018-01-22T13:45:50Z
dc.date.available2018-01-22T13:45:50Z
dc.date.issued2017-10
dc.identifier.citationTaç, D. , Aytaç, İ. A., Karatavuk, A. O., Kuş, M., Ziyanak, F., and A., L. (2017). Iron-promoted 1,5-substitution (SN2′′) reactions of enyne acetates and oxiranes with Grignard reagents. Asian Journal of Organic Chemistry, 6(10), 1415-1420. doi:10.1002/ajoc.201700225en_US
dc.identifier.issn2193-5807
dc.identifier.urihttp://doi.org/10.1002/ajoc.201700225
dc.identifier.urihttp://hdl.handle.net/11147/6723
dc.description.abstractAcetate derivatives of 2-en-4-yne alcohols 1 and enyne oxiranes 4 regioselectively underwent 1,5-substitution (SN2′′) reactions with Grignard reagents in the presence of an iron compound to provide vinylallenes exclusively with the (E)-configuration. An alkali salt was needed to avoid the hydride-promoted reductive 1,5-substitution pathway for 1, whereas no such additive was needed for the effective conversion of 4 into the desired alkylated or arylated vinylallene structure.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (113Z155)en_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relationinfo:eu-repo/grantAgreement/TUBITAK/KBAG/113Z155en_US
dc.relation.isversionof10.1002/ajoc.201700225en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectRegioselectivityen_US
dc.subjectNucleophilic substitutionen_US
dc.subjectGrignard reactionen_US
dc.subjectEnynesen_US
dc.titleIron-promoted 1,5-substitution (SN2′′) reactions of enyne acetates and oxiranes with Grignard reagentsen_US
dc.typearticleen_US
dc.contributor.authorIDTR1860en_US
dc.contributor.iztechauthorTaç, Doğan
dc.contributor.iztechauthorAytaç, İsmet Arınç
dc.contributor.iztechauthorKuş, Melih
dc.contributor.iztechauthorZiyanak, Fırat
dc.contributor.iztechauthorArtok, Levent
dc.relation.journalAsian Journal of Organic Chemistryen_US
dc.contributor.departmentİYTE, Fen Fakültesi, Kimya Bölümüen_US
dc.identifier.volume6en_US
dc.identifier.issue10en_US
dc.identifier.startpage1415en_US
dc.identifier.endpage1420en_US
dc.identifier.wosWOS:000413355100017
dc.identifier.scopusSCOPUS.2-s2.0-85025070187
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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