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Synthesis and characterization of nitrosyl[tris(3,5dimethylpyrazolyl) borato]molybdenum complexes containing aryloxo, arylamido and arylcyano ligands
The complexes [MoTp*(NO)X(ZC6H4CN-p)] [Tp* = 3,5-dimethylpyrazolyl; X = Cl, Z = O and NH; X = I, Z = CN) were prepared and characterized using 1H-NMR, IR, FAB mass spectroscopy and micro analysis.
Reactions of the solvent-stabilized compound [MoOCl2(THF)2] with aromatic nitrogen donor ligands: Spectroscopic characterization and semiempirical AM1* calculations
Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2]withP Ph3 yielded the oxomolybdenum(IV) species [MoOCl2 (THF)2](1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl2 (=NC6 ...
Genetic multivariate calibration methods for near infrared (NIR) spectroscopic determination of complex mixtures
The simultaneous determination of ternary mixtures of methylene chloride, ethyl acetate, and methanol using near infrared (NIR) spectroscopy and 4 different genetic algorithms based multivariate calibration methods was ...