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Synthesis and characterization of nitrosyl[tris(3,5dimethylpyrazolyl) borato]molybdenum complexes containing aryloxo, arylamido and arylcyano ligands
The complexes [MoTp*(NO)X(ZC6H4CN-p)] [Tp* = 3,5-dimethylpyrazolyl; X = Cl, Z = O and NH; X = I, Z = CN) were prepared and characterized using 1H-NMR, IR, FAB mass spectroscopy and micro analysis.
Reactions of the solvent-stabilized compound [MoOCl2(THF)2] with aromatic nitrogen donor ligands: Spectroscopic characterization and semiempirical AM1* calculations
Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2]withP Ph3 yielded the oxomolybdenum(IV) species [MoOCl2 (THF)2](1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl2 (=NC6 ...