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dc.contributor.advisorArtok, Leventen
dc.contributor.authorKaragöz, Ezgi Şuleen
dc.date.accessioned2014-07-22T13:51:54Z
dc.date.available2014-07-22T13:51:54Z
dc.date.issued2013en
dc.identifier.urihttp://hdl.handle.net/11147/3593
dc.descriptionThesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2013en
dc.descriptionIncludes bibliographical references (leaves: 68-72)en
dc.descriptionText in English; Abstract: Turkish and Englishen
dc.descriptionxiii, 199 leavesen
dc.descriptionFull text release delayed at author's request until 2016.04.21en
dc.description.abstractTransition metal-catalyzed carbon-carbon bond formation reactions are well-rounded methods to synthetic organic chemistry. One type of these reactions is the alkoxycarbonylation reactions performed in the presence of a transition metal catalyst, an alcohol and carbon monoxide atmosphere. Investigations on palladium-catalyzed alkoxycarbonylation reaction of allylic compounds leading to β,γ-unsaturated esters have been performed. Moreover propargyl derivatives are prominent reactants for palladium-catalyzed alkoxycarbonylation reactions to yield allene esters which proceed through a σ-allenylpalladium intermediate. Palladium-catalyzed alkoxycarbonylation reaction of some enantio-enriched propargylic derivatives that facilitate unique centre-to-axis chirality transfer is still inadequate and essential. In this study, the palladium-catalyzed alkoxycarbonylation reaction of E-configured 2,4-enyne carbonates which afforded exclusively ester functionalized (E)-configured vinylallenes through the formation of σ-vinylallenylpalladium species was performed. Moreover the chirality transfer of the proposed method was also surveyed over an enantio-enriched E-enyne carbonate.en
dc.language.isoengen
dc.publisherİzmir Institute of Technologyen
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.subject.lcshPalladiumen
dc.subject.lcshPalladium catalystsen
dc.subject.lcshCarbonatesen
dc.titlePalladium-catalyzed alkoxycarbonylation reactions of (E)-2-en-4-yne carbonatesen
dc.typemasterThesisen
dc.contributor.departmentİzmir Institute of Technology. Chemistryen
dc.relation.publicationcategoryTezen_US


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