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dc.contributor.authorÖlçer, Yekta Arya
dc.contributor.authorDemirkurt, Merve
dc.contributor.authorDemir, Mustafa M.
dc.contributor.authorEroğlu, Ahmet E.
dc.date.accessioned2017-10-03T08:50:50Z
dc.date.available2017-10-03T08:50:50Z
dc.date.issued2017
dc.identifier.citationÖlçer, Y. A., Demirkurt, M., Demir, M. M., and Eroğlu, A. E. (2017). Development of molecularly imprinted polymers (MIPs) as a solid phase extraction (SPE) sorbent for the determination of ibuprofen in water. RSC Advances, 7(50), 31441-31447. doi:10.1039/c7ra05254een_US
dc.identifier.issn2046-2069
dc.identifier.urihttp://doi.org/10.1039/c7ra05254e
dc.identifier.urihttp://hdl.handle.net/11147/6297
dc.description.abstractIbuprofen is a well-known endocrine disrupter. In this study, highly selective molecularly imprinted polymers (MIPs) with different morphologies were synthesized via precipitation and bulk polymerization of methacrylic acid (MAA) and trimethylolpropane trimethacrylate (TRIM) in the presence of ibuprofen as a template. Non-imprinted polymers (NIPs) were also synthesized via the same procedure in the absence of ibuprofen. Spherical and monolithic MIPs were obtained using different experimental conditions, and the spherical MIP was shown to have better sorption towards ibuprofen. The optimum sample pH, sorbent amount, sample volume, and sorption time were determined to be 8.0, 25.0 mg, 10.0 mL, and 30.0 min, respectively. A methanol water mixture (MeOH:H2O, 80:20, pH 3.0) was employed as an eluent with >97% (±0.8, n = 3) desorption. The MIP demonstrated high selectivity towards ibuprofen in the presence of naproxen and ketoprofen. The validity of the proposed method was checked via spike recovery tests using drinking and tap water samples. The method worked efficiently for both water types, resulting in the recoveries of 97.2% (±0.3, n = 3) and 97.7% (±0.2, n = 3).en_US
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (TUBITAK 114Z777)en_US
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relationinfo:eu-repo/grantAgreement/TUBITAK/KBAG/114Z777en_US
dc.relation.isversionof10.1039/c7ra05254een_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectEndocrine disruptersen_US
dc.subjectDrug productsen_US
dc.subjectMolecularly imprinted polymersen_US
dc.subjectBulk polymerizationen_US
dc.titleDevelopment of molecularly imprinted polymers (MIPs) as a solid phase extraction (SPE) sorbent for the determination of ibuprofen in wateren_US
dc.typearticleen_US
dc.contributor.authorIDTR130614en_US
dc.contributor.authorIDTR8641en_US
dc.contributor.iztechauthorÖlçer, Yekta Arya
dc.contributor.iztechauthorDemirkurt, Merve
dc.contributor.iztechauthorDemir, Mustafa M.
dc.contributor.iztechauthorEroğlu, Ahmet E.
dc.relation.journalRSC Advancesen_US
dc.contributor.departmentİYTE, Fen Fakültesi, Kimya Bölümüen_US
dc.identifier.volume7en_US
dc.identifier.issue50en_US
dc.identifier.startpage31441en_US
dc.identifier.endpage31447en_US
dc.identifier.wosWOS:000404076400035
dc.identifier.scopusSCOPUS:2-s2.0-85021662789
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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