Show simple item record

dc.contributor.authorKılınç, Emre
dc.contributor.authorYılmaz, Selahattin
dc.date.accessioned2017-07-07T13:49:12Z
dc.date.available2017-07-07T13:49:12Z
dc.date.issued2015-05-20
dc.identifier.citationKılıç, E., and Yılmaz, S. (2015). Fructose dehydration to 5-hydroxymethylfurfural over sulfated TiO2-SiO2, Ti-SBA-15, ZrO2, SiO2, and activated carbon catalysts. Industrial and Engineering Chemistry Research, 54(19), 52209-5225. doi:10.1021/acs.iecr.5b00628en_US
dc.identifier.issn0888-5885
dc.identifier.urihttps://doi.org/10.1021/acs.iecr.5b00628
dc.identifier.urihttp://hdl.handle.net/11147/5895
dc.description.abstractDifferent sulfated catalysts including SO4/TiO2-SiO2, SO4/Ti-SBA-15, SO4/ZrO2, SO4/AC, and SO4/SiO2 were tested in fructose dehydration to 5-hydroxymethylfurfural (HMF). Reactions were carried out in dimethyl sulfoxide (DMSO) at 110 °C. Characterization results indicated that no sulfur leaching was observed from SO4/ZrO2, SO4/TiO2-SiO2, and SO4/Ti-SBA-15 catalysts in the reaction tests. The SO4/TiO2-SiO2 catalyst had a high amount of strong acid sites and the highest amount of Bronsted sites. The highest selectivity to HMF at high conversion, that is, 89% selectivity at 77% fructose conversion was obtained over this catalyst. It preserved its activity after four times reuse.Activated carbonCarbonCatalystsDehydrationen_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.isversionof10.1021/acs.iecr.5b00628en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectActivated carbonen_US
dc.subjectCatalystsen_US
dc.subjectDehydrationen_US
dc.subjectCatalyst selectivityen_US
dc.subjectDimethyl sulfoxideen_US
dc.subjectOrganic solventsen_US
dc.titleFructose dehydration to 5-hydroxymethylfurfural over sulfated TiO2-SiO2, Ti-SBA-15, ZrO2, SiO2, and activated carbon catalystsen_US
dc.typearticleen_US
dc.contributor.authorIDTR22592en_US
dc.contributor.iztechauthorKılınç, Emre
dc.contributor.iztechauthorYılmaz, Selahattin
dc.relation.journalIndustrial and Engineering Chemistry Researchen_US
dc.contributor.departmentİYTE, Mühendislik Fakültesi, İnşaat Mühendisliği Bölümüen_US
dc.identifier.volume54en_US
dc.identifier.issue19en_US
dc.identifier.startpage5220en_US
dc.identifier.endpage5225en_US
dc.identifier.wosWOS:000355054400004
dc.identifier.scopusSCOPUS:2-s2.0-84930225823
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record