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dc.contributor.authorZielinski, John M.
dc.contributor.authorAlsoy, Sacide
dc.date.accessioned2016-05-09T08:38:38Z
dc.date.available2016-05-09T08:38:38Z
dc.date.issued2001-07
dc.identifier.citationZielinski, J. M., and Alsoy, S. (2001). Onsager consistency checks for multicomponent diffusion models. Journal of Polymer Science, Part B: Polymer Physics, 39(13), 1496-1504, doi:10.1002/polb.1121en_US
dc.identifier.issn0887-6266
dc.identifier.urihttp://doi.org/10.1002/polb.1121
dc.identifier.urihttp://hdl.handle.net/11147/4612
dc.description.abstractThe Onsager reciprocity relations are applied to several recently proposed multicomponent diffusion models in an attempt to gauge their validity and ascertain their applicability. Each of these friction-based diffusion models stems from the more general Bearman formalism through various assumptions regarding the individual friction coefficients. By assessing the compliance of the Bearman model with respect to the Onsager relations, we ascertain the validity of the simplifications introduced to each diffusion model and suggest which postulates lead to results consistent with the Onsager relations. Although some models are not consistent with the Onsager relations, each model predicts the multicomponent drying of polymer films reasonably well. The necessity for consistency with the Onsager development is, therefore, revisited.en_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.isversionof10.1002/polb.1121en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCross coefficientsen_US
dc.subjectDryingen_US
dc.subjectFriction coefficientsen_US
dc.subjectMulticomponent diffusionen_US
dc.subjectMutual diffusionen_US
dc.subjectOnsageren_US
dc.subjectSelf-diffusionen_US
dc.titleOnsager consistency checks for multicomponent diffusion modelsen_US
dc.typearticleen_US
dc.contributor.authorIDTR2091en_US
dc.contributor.iztechauthorAlsoy, Sacide
dc.relation.journalJournal of Polymer Science, Part B: Polymer Physicsen_US
dc.contributor.departmentIzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume39en_US
dc.identifier.issue13en_US
dc.identifier.startpage1496en_US
dc.identifier.endpage1504en_US
dc.identifier.wosWOS:000169210300007
dc.identifier.scopusSCOPUS:2-s2.0-0035399144


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