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dc.contributor.authorEroğlu, Ahmet E.en_US
dc.contributor.authorMcLeod, Cameron W.en_US
dc.contributor.authorLeonard, Kinson S.en_US
dc.contributor.authorMcCubbin, Daviden_US
dc.date.accessioned2014-07-25T03:25:26Z
dc.date.available2014-07-25T03:25:26Z
dc.date.issued1998-07-06en_US
dc.identifier.citationEroğlu, Ahmet E., McLeod, Cameron W., Leonard, Kinson S., & McCubbin, D. (1998). Determination of plutonium in seawater using co-precipitation and inductively coupled plasma mass spectrometry with ultrasonic nebulisation1. Spectrochimica Acta Part B: Atomic Spectroscopy, 53(6–8), 1221–1233. doi:10.1016/S0584-8547(98)00179-7en_US
dc.identifier.issn0584-8547en_US
dc.identifier.urihttp://doi:10.1016/S0584-8547(98)00179-7en_US
dc.identifier.urihttp://hdl.handle.net/11147/4084
dc.description.abstractA flow injection–inductively coupled plasma–mass spectrometric (FI–ICP–MS) procedure, utilising ultrasonic nebulisation with membrane desolvation (USN/MD), has been developed for the determination of plutonium (Pu) in seawater at fg l−1 concentration levels. Seawater samples (1 l), after filtration, were subjected to co-precipitation with NdF3, followed by ion exchange to enrich Pu and to reject seawater matrix ions and co-existing uranium. The seawater concentrate (1.0 ml) was then analysed by FI–ICP–MS. The limit of detection for in seawater based on an enrichment factor of 1000 was 5 fg l−1, and precision at the 0.80 pg l−1 level was 12% RSD. Accuracy was verified via recovery experiments, and by comparing survey data for the Irish Sea with that derived by standard methodology based on co-precipitation and α-spectrometry. Concentrations for dissolved in the Irish Sea were in the range of 0.267–0.941 pg l−1 (0.614–2.164 mBq l−1) and 0.051–0.196 pg l−1 (0.428–1.646 mBq l−1), respectively.en_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.relation.isversionof10.1016/S0584-8547(98)00179-7en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPlutoniumen_US
dc.subjectSeawateren_US
dc.subjectInductively coupled plasma–mass spectrometry (ICP–MS)en_US
dc.subjectFlow injectionen_US
dc.subjectUltrasonic nebulisationen_US
dc.titleDetermination of plutonium in seawater using co-precipitation and inductively coupled plasma mass spectrometry with ultrasonic nebulisation1en_US
dc.typearticleen_US
dc.contributor.authorIDTR8641
dc.contributor.iztechauthorEroğlu, Ahmet E.en_US


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